ON THE RHODIUM-CATALYZED FORMATION OF ACETIC-ACID FROM METHYL FORMATE - COMPARISON WITH THE RHODIUM-CATALYZED FORMATION OF ACETIC-ACID BY DIRECT CARBONYLATION OF METHANOL

被引：4

作者：

BUB, G ^{[1
]}

HOG, HU ^{[1
]}

机构：

[1] HULS AKTIENGESELL MARL,D-45772 MARL,GERMANY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1995年 / 95卷 / 01期

关键词：

ACETIC ACID; CARBONYLATION; METHANOL; METHYL FORMATE; RHODIUM;

D O I：

10.1016/1381-1169(94)00161-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In presence of the homogenous Rh/Cr/I catalyst system methyl formate can be isomerized to acetic acid under CO-pressure with high conversion rates and excellent selectivity. This catalyst system has never been applied before for this reaction.

引用

页码：45 / 52

页数：8

共 10 条

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[5] HOG HU, 1985, Patent No. 105132
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[8] Rizkalla N., 1976, DE, Patent No. 2610036
[9] A HIGHLY EFFICIENT CATALYST SYSTEM FOR THE ISOMERIZATION OF METHYL FORMATE TO ACETIC-ACID
SCHRECK, DJ
BUSBY, DC
WEGMAN, RW
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1988, 47 (01): : 117 - 121
[10] TOMIYA L, 1979, Patent No. 2007666

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