ON THE RHODIUM-CATALYZED FORMATION OF ACETIC-ACID FROM METHYL FORMATE - COMPARISON WITH THE RHODIUM-CATALYZED FORMATION OF ACETIC-ACID BY DIRECT CARBONYLATION OF METHANOL

被引：4

作者：

BUB, G ^{[1
]}

HOG, HU ^{[1
]}

机构：

[1] HULS AKTIENGESELL MARL,D-45772 MARL,GERMANY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1995年 / 95卷 / 01期

关键词：

ACETIC ACID; CARBONYLATION; METHANOL; METHYL FORMATE; RHODIUM;

D O I：

10.1016/1381-1169(94)00161-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In presence of the homogenous Rh/Cr/I catalyst system methyl formate can be isomerized to acetic acid under CO-pressure with high conversion rates and excellent selectivity. This catalyst system has never been applied before for this reaction.

引用

页码：45 / 52

页数：8

共 10 条

[1]

BRYANT FJ, 1973, APR AM CHEM SOC DALL

[2] HALIDE CATALYSIS OF OXIDATIVE ADDITION OF ALKYL-HALIDES TO RHODIUM(I) COMPLEXES [J].

FORSTER, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (04) :951-952

[3] MECHANISM OF A RHODIUM-COMPLEX-CATALYZED CARBONYLATION OF METHANOL TO ACETIC-ACID [J].

FORSTER, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (03) :846-848

[4]

FORSTER D, 1979, ADV ORGANOMET CHEM, V17, P285

[5]

HOG HU, 1985, Patent No. 105132

[6]

KUCKERTS H, 1976, Patent No. 2450965

[7]

PAULIK FE, 1968, J CHEM SOC CHEM COMM, P1578

[8]

Rizkalla N., 1976, DE, Patent No. 2610036

[9] A HIGHLY EFFICIENT CATALYST SYSTEM FOR THE ISOMERIZATION OF METHYL FORMATE TO ACETIC-ACID [J].

SCHRECK, DJ ;

BUSBY, DC ;

WEGMAN, RW .

JOURNAL OF MOLECULAR CATALYSIS, 1988, 47 (01) :117-121

[10]

TOMIYA L, 1979, Patent No. 2007666

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