10-14-[(2-Hydroxybenzylidene)amino]phenyll-5,5-difluoro-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2 ',1 '-f][1,3,2]diaza- borinin-4-ium-5-uide

被引：0
作者：
Li, Zhensheng [1 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Ma, Zhongguancun Donglu 29, Beijing 100190, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813015523
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C26H24BF2N3O, comprises a borondipyrromethene (BODIPY) framework and a phenolic Schiff base substituent group. The BODIPY unit is close to planar [maximum deviation from the least -squares plane = 0.040 (3) angstrom], and forms a dihedral angle of 80.38 (13)degrees with the meso-substituent phenyl ring and an angle of 56.57 (13)degrees with the phenolic ring in the extended substituent chain. An intramolecular O-H center dot center dot center dot N hydrogen bond is formed between the phenolic hydroxyl group and the Schiff base N-atom. The crystal studied was a non-merohedral twin with a BASF factor of 0.447 (3) for the two components.
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页码：O1072 / +
页数：9
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