INFLUENCE OF SOLVENTS ON HYDRATION OF 1,2-EPOXYHEXANE OVER H-ZSM-5-C18 CATALYST

被引：6

作者：

OGAWA, H ^{[1
]}

SAWAMURA, K ^{[1
]}

CHIHARA, T ^{[1
]}

机构：

[1] INST PHYS & CHEM RES,WAKO,SAITAMA 35101,JAPAN

来源：

CATALYSIS LETTERS | 1993年 / 18卷 / 04期

关键词：

ZSM-5; HYDRATION OF EPOXIDE; SOLVENT EFFECT; SHAPE-SELECTIVE PROPERTY; PORE SIZE;

D O I：

10.1007/BF00765283

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of solvents such as benzene, toluene, m-xylene, and neighbours on the hydration of 1,2-epoxyhexane caused by the pore of H-ZSM-5-C18 catalyst was studied by measurement of the reaction rate. The largest retardation of the hydration was observed using m-xylene as solvent. Any other solvents did not show so large a retardation as that of m-xylene. By taking advantage of the retardation with m-xylene the effect of the pores of various types of zeolites on the rate could be dynamically demonstrated.

引用

页码：367 / 371

页数：5

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