VOLUMES AND HEAT-CAPACITIES OF BINARY NONAQUEOUS MIXTURES .1. THE SYSTEMS ACETONITRILE FORMAMIDE AND ACETONITRILE N-METHYLFORMAMIDE

被引：19

作者：

KOLKER, AM

KULIKOV, MV

KRESTOV, AG

机构：

[1] Institute of Non-Aqueous Solution Chemistry, the Russian Academy of Sciences, Ivanovo, 153045

来源：

THERMOCHIMICA ACTA | 1992年 / 211卷

关键词：

D O I：

10.1016/0040-6031(92)87007-W

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The density and heat capacity of the binary mixtures acetonitrile-formamide and acetonitrile-N-methylformamide were measured over the entire range of compositions at 283.15-328.15 K. The excess and apparent molar volumes and heat capacities of the mixtures studied were calculated. An analysis of the experimental and calculated data was carried out. Relationships between the nature of the substances, and the temperature and composition on the thermodynamic properties of acetonitrile mixtures with formamide and N-methylformamide are revealed.

引用

页码：61 / 72

页数：12

共 14 条

[1]

[Anonymous], ION SOLVATION

[2]

KARAMYAN GG, 1981, RUSS J APPL CHEM, V22, P54

[3] LIGHT-SCATTERING FROM BINARY-MIXTURES OF 1,2-DICHLOROETHANE, ACETONITRILE, DIMETHYLFORMAMIDE AND ETHYL-ACETATE - EXCESS GIBBS FUNCTIONS [J].