ELECTROCHEMICAL AND OPTICAL-PROPERTIES OF POLY(3-METHYLTHIOPHENES) ELECTROSYNTHESIZED BY 3,3'-4,4'-DIMETHYL-2,2'-BITHIOPHENES, 3,4'-4,4'-DIMETHYL-2,2'-BITHIOPHENES AND 4,4'-DIMETHYL-2,2'-BITHIOPHENES

被引：36

作者：

ARBIZZANI, C ^{[1
]}

BARBARELLA, G ^{[1
]}

BONGINI, A ^{[1
]}

MASTRAGOSTINO, M ^{[1
]}

ZAMBIANCHI, M ^{[1
]}

机构：

[1] CNR,ICOCEA,I-40064 OZZANO EMILIA,ITALY

来源：

SYNTHETIC METALS | 1992年 / 52卷 / 03期

关键词：

D O I：

10.1016/0379-6779(92)90032-E

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The 3,3'-, 3,4'- and 4,4'-dimethyl-2,2'-bithiophenes, prepared in very pure form and characterized by C-13 NMR, were used as starting molecules for electrochemical polymerization of poly(3-methylthiophenes). The optical properties of the resulting polymers were interpreted on the basis of the conformation of the starting dimers determined by force field MMP2 calculations.

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页码：329 / 339

页数：11

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