EVALUATION OF THE KINETIC AND THERMODYNAMIC PARAMETERS FOR THE THERMAL-DECOMPOSITION OF BIS(ETA-5-CYCLOPENTADIENYL)TITANIUM(IV) N,N'-BIS(2-HYDROXYNAPHTHALENE-1-CARBALDENE)ALKENEDIAMINES

被引：0

作者：

JOSHI, V ^{[1
]}

JAIN, SK ^{[1
]}

KAUSHIK, NK ^{[1
]}

机构：

[1] UNIV DELHI,DEPT CHEM,DELHI 110007,INDIA

来源：

THERMOCHIMICA ACTA | 1992年 / 203卷

关键词：

D O I：

10.1016/0040-6031(92)85206-B

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The course of the thermal degradation of (eta-5-C5H5)2Ti(SB) complexes (SB, Schiff base) has been investigated using thermogravimetric (TG) and differential thermal analysis (DTA) techniques. The order of reaction and activation energy were calculated from the TG curves and the enthalpy change was calculated from the DTA curve. From the evaluated kinetic parameters, a mechanism was suggested for the thermal degradation. Spectral studies (IR, H-1-NMR and UV-visible) indicate that these complexes are tetradentate and octahedral.

引用

页码：311 / 320

页数：10

共 38 条

[31] METALLOPHOSPHANE SULFIDES DERIVED FROM BIS-CYCLOPENTADIENYL TANTALUM .2. SYNTHESIS OF HETEROBIMETALLIC COMPLEXES CP(2)TA(H-2)(MU,ETA(1)ETA(1)-PR(2)S)M'L(N) (R=ME,PH, M'L(N)=CR(CO)(5), MO(CO)(5), W(CO)(5), CPMN(CO)(2), FE(CO)(4))
CHALLET, S
LEBLANC, JC
MOISE, C
NEW JOURNAL OF CHEMISTRY, 1995, 19 (11) : 1139 - 1143
[32] SYNTHESIS AND THERMAL-DECOMPOSITION OF THE CHELATED SULFONIUM SALTS, (FE(ETA-5-C5H5)(CO)[CH2S(PH)(CH2)NCH=CH2])BF4, N=1,2
BAREFIELD, EK
MCCARTEN, P
HILLHOUSE, MC
VANDERVEER, DG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 68 - INOR
[33] The crystal structure of 6,6′-(((2-(dimethylamino) ethyl)azanediyl)bis(methylene))bis(benzo[d][1,3] dioxol-5-ol ato-κ4N,N′,O,O′)-(pyridine-2,6-dicarboxylato-N,O,O′)-titanium(IV)-dichloromethane(1/1), C27H25N3O10Ti
Li, Shanjia
Wang, Peng
Ji, Mingyu
Yang, Mingjun
Pu, Xiuying
Zhao, Tiankun
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2021, 236 (06): : 1165 - 1167
[34] FORMATION AND CRYSTAL-STRUCTURE OF TRANS-BIS(ACETONITRILE)TRIS-(ETA-5-CYCLOPENTADIENYL)URANIUM(IV) TETRACHLORO-TRANS-DIOXOURANATE(VI) - A NOVEL SPECIES INVOLVING THE 1ST CATIONIC ORGANO-F-METAL COMPLEX AND URANIUM IN 2 DIFFERENT OXIDATION-STATES
BOMBIERI, G
BENETOLLO, F
KLAHNE, E
FISCHER, RD
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (06): : 1115 - 1121
[35] Synthesis, Characterization, Thermal Decomposition and Antifungal Studies of Cr(III), Mn(II), Fe(III), Co(II), Ni(II) and Cu(II) Complexes of N,N'-bis[1,3-benzodioxol-5ylmethylene]ethane-1, 2-diamine
Alex, Prasad M.
Aravindakshan, K. K.
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2009, 39 (10) : 718 - 733
[36] Effect of trimethylaluminum on the formation of active sites of the catalytic system bis[N-(3,5-di-tert-butylsalicylidene)-2,3,5,6-tetrafluoroanilinato]titanium(IV) dichloride—MAO and catalytic isomerization of hex-1-ene
N. M. Bravaya
E. E. Faingol’d
O. N. Babkina
L. A. Petrova
V. D. Makhaev
S. Ch. Gagieva
V. A. Tuskaev
B. M. Bulychev
Russian Chemical Bulletin, 2011, 60 : 1461 - 1468
[37] Effect of trimethylaluminum on the formation of active sites of the catalytic system bis[N-(3,5-di-tert-butylsalicylidene)-2,3,5,6-tetrafluoroanilinato]titanium(IV) dichloride-MAO and catalytic isomerization of hex-1-ene
Bravaya, N. M.
Faingol'd, E. E.
Babkina, O. N.
Petrova, L. A.
Makhaev, V. D.
Gagieva, S. Ch
Tuskaev, V. A.
Bulychev, B. M.
RUSSIAN CHEMICAL BULLETIN, 2011, 60 (07) : 1461 - 1468
[38] 1,4-Diaza-1,3-diene (DAD) complexes of early transition elements.: Syntheses, structures and molecular dynamics of mono- and bis(η5-cyclopentadienyl)titanium-, zirconium- and hafnium(DAD) complexes.: Crystal- and molecular structures of CpTi(DAD)CH2Ph, [CpTi(DAD)]2O, CpZr[(DAD)(N∧O)] and Cp2Hf(DAD)
Scholz, J
Hadi, GA
Thiele, KH
Görls, H
Weimann, R
Schumann, H
Sieler, J
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 626 (1-2) : 243 - 259

← 1 2 3 4 →