EVALUATION OF THE KINETIC AND THERMODYNAMIC PARAMETERS FOR THE THERMAL-DECOMPOSITION OF BIS(ETA-5-CYCLOPENTADIENYL)TITANIUM(IV) N,N'-BIS(2-HYDROXYNAPHTHALENE-1-CARBALDENE)ALKENEDIAMINES

被引：0
|
作者：
JOSHI, V [1 ]
JAIN, SK [1 ]
KAUSHIK, NK [1 ]
机构：
[1] UNIV DELHI,DEPT CHEM,DELHI 110007,INDIA
来源：
THERMOCHIMICA ACTA | 1992年 / 203卷
关键词：
D O I：
10.1016/0040-6031(92)85206-B
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The course of the thermal degradation of (eta-5-C5H5)2Ti(SB) complexes (SB, Schiff base) has been investigated using thermogravimetric (TG) and differential thermal analysis (DTA) techniques. The order of reaction and activation energy were calculated from the TG curves and the enthalpy change was calculated from the DTA curve. From the evaluated kinetic parameters, a mechanism was suggested for the thermal degradation. Spectral studies (IR, H-1-NMR and UV-visible) indicate that these complexes are tetradentate and octahedral.
引用
收藏
页码：311 / 320
页数：10
相关论文
共 38 条
  • [11] {2-[(η5-Cyclopentadienyl)diphenylmethyl]-1H-imidazolido-κN}-bis(N,N-diethylamido)titanium(IV)
    Cai, Xianfeng
    Xu, Yingying
    Nie, Wanli
    Borzov, Maxim V.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M549 - U470
  • [12] 5-COORDINATE BENT METALLOCENES - CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(ETA-5-CYCLOPENTADIENYL)CHLORO-(N,N-DIMETHYLMONOTHIOCARBAMATO)ZIRCONIUM(IV)
    SILVER, ME
    FAY, RC
    ORGANOMETALLICS, 1983, 2 (01) : 44 - 47
  • [13] KINETIC ASPECTS OF THE PROCESS OF THERMAL-DECOMPOSITION OF N,N'-BIS(7-OXOBICYCLO-2,2,1,5-HEPTENE)DICARBOXIMIDE
    GHERASIM, GM
    SAVA, M
    REVISTA DE CHIMIE, 1985, 36 (05): : 393 - 396
  • [14] STRUCTURE OF ACETAMIDINE(BROMO)BIS(ETA-5-CYCLOPENTADIENYL)TUNGSTEN(IV) HEXAFLUOROPHOSPHATE, [W(ETA-5-C5H5)2BR(C2H6N2)][PF6]
    CARRONDO, MAAFDT
    FELIX, V
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 2451 - 2453
  • [15] N7/O6 CHELATION IN A COMPLEX WITH AN ANALOG OF GUANINE - PREPARATION, SPECTROSCOPIC STUDY, AND CRYSTAL-STRUCTURE OF BIS(ETA-5-CYCLOPENTADIENYL)(THEOPHYLLINATO)TITANIUM(III)
    COZAK, D
    MARDHY, A
    OLIVIER, MJ
    BEAUCHAMP, AL
    INORGANIC CHEMISTRY, 1986, 25 (15) : 2600 - 2606
  • [16] KINETIC-PARAMETERS OF THERMAL-DECOMPOSITION OF BIS(2-OH-1-NAPHTHALDOXIME) CHELATES USING FREEMAN-CARROLL EQUATION
    NAIDU, RS
    RUBY, R
    RAO, EN
    MALLIKARJUN, KG
    THERMOCHIMICA ACTA, 1989, 140 : 97 - 102
  • [17] ETA-5-CYCLOPENTADIENYL AND ETA-5-METHYLCYCLOPENTADIENYL 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE COMPLEXES OF TITANIUM(II) - THE CRYSTAL-STRUCTURE OF TI(C5H4ME)2(DMPE)
    GIROLAMI, GS
    WILKINSON, G
    THORNTONPETT, M
    HURSTHOUSE, MB
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (10): : 2347 - 2350
  • [18] AN EXAMPLE OF THE THERMAL-DECOMPOSITION OF A CRYSTALLINE POLYMER - POLY(1,6-BIS(N-CARBAZOLYL)-2,4-HEXADIYNE)
    BRADNER, FP
    SHAPIRO, JS
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1992, 193 (02): : 389 - 397
  • [19] OXIDATIVE COUPLING OF PHENYLETHYNYL GROUP IN MU-(1-3ETA-2-4ETA-TRANS-TRANS-1,4-DIPHENYLBUTADIENE)BIS(BIS(N5-METHYLCYCLOPENTADIENYL)TITANIUM
    SEKUTOWSKI, DG
    STUCKY, GD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1975, 170 (AUG24): : 38 - 38
  • [20] Evaluation of thermal hazards and thermo-kinetic parameters of N,N'-dinitro-4,4'-azo-Bis(1,2,4-triazolone) (DNZTO)
    Zhu, Jiaping
    Jin, Shaohua
    Yu, Yuehai
    Zhang, Chunyuan
    Li, Lilijie
    Chen, Shusen
    Shu, Qinghai
    THERMOCHIMICA ACTA, 2016, 623 : 58 - 64
1234