LEVELS, PROFILE AND PATTERN OF PCDDS AND PCDFS IN SAMPLES RELATED TO THE PRODUCTION AND USE OF CHLORINE

被引:51
作者
RAPPE, C [1 ]
KJELLER, LO [1 ]
KULP, SE [1 ]
DEWIT, C [1 ]
HASSELSTEN, I [1 ]
PALM, O [1 ]
机构
[1] SWEDISH ENVIRONM PROTECT AGCY,S-17185 SOLNA,SWEDEN
关键词
D O I
10.1016/0045-6535(91)90010-B
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Analyses of sludge from graphite electrodes used in the chloralkali process show total levels of PCDFs as high as 650000 pg/g sludge. The levels of tetra-, penta- and hexaCDFs were found to be approximately the same. The levels for the corresponding PCDDs were below the detection level. The dominating congeners within each group are the toxic 2,3,7,8-substituted PCDFs at levels of 340000 pg/g, This typical pattern, called the "chloralkli pattern" can also be found in soil samples taken at another chloralkali plant. The typical pattern can also be identified in a solution of ferric chloride. Traces of "chloralkali pattern" are identified in a sludge sample from the drinking water purification plant, the source for PCDFs in the sludge is unknown.
引用
收藏
页码:1629 / 1636
页数:8
相关论文
共 7 条
  • [1] NORDIC RISK ASSESSMENT OF PCDDS AND PCDFS
    AHLBORG, UG
    [J]. CHEMOSPHERE, 1989, 19 (1-6) : 603 - 608
  • [2] SEARCH FOR INDUSTRIAL SOURCES OF PCDD PCDFS .2. METAL CHLORIDES
    HEINDL, A
    HUTZINGER, O
    [J]. CHEMOSPHERE, 1986, 15 (05) : 653 - 658
  • [3] JONSSON P, UNPUB
  • [4] FORMATION OF PCDDS AND PCDFS BY THE CHLORINATION OF WATER
    RAPPE, C
    SWANSON, SE
    GLAS, B
    KRINGSTAD, KP
    DESOUSA, P
    ABE, Z
    [J]. CHEMOSPHERE, 1989, 19 (12) : 1875 - 1880
  • [5] LEVELS OF PCDDS AND PCDFS IN PRODUCTS AND EFFLUENT FROM THE SWEDISH PULP AND PAPER-INDUSTRY AND CHLORALKALI PROCESS
    RAPPE, C
    GLAS, B
    KJELLER, LO
    KULP, SE
    DEWIT, C
    MELIN, A
    [J]. CHEMOSPHERE, 1990, 20 (10-12) : 1701 - 1706
  • [6] ANALYSES OF PCDDS AND PCDFS IN SLUDGE AND WATER SAMPLES
    RAPPE, C
    KJELLER, LO
    ANDERSSON, R
    [J]. CHEMOSPHERE, 1989, 19 (1-6) : 13 - 20
  • [7] SWANSON SE, 1988, THESIS U UMEA