ISOTACTIC POLYMETHOXY-1-ALKENES FROM THE TERRESTRIAL BLUE-GREEN-ALGA SCYTONEMA-OCELLATUM - STRUCTURE AND SYNTHESIS

被引：15

作者：

MORI, Y ^{[1
]}

KOHCHI, Y ^{[1
]}

NOGUCHI, H ^{[1
]}

SUZUKI, M ^{[1
]}

CARMELI, S ^{[1
]}

MOORE, RE ^{[1
]}

PATTERSON, GML ^{[1
]}

机构：

[1] UNIV HAWAII,DEPT CHEM,HONOLULU,HI 96822

来源：

TETRAHEDRON | 1991年 / 47卷 / 27期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4020(01)80955-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel isotactic polymethoxy-1-alkenes 2-5 were isolated from the tolytoxin-producing blue-green alga Scytonema ocellatum. The gross structures and relative configurations were determined by NMR and mass spectral analysis. Synthesis of optically active 2-4 in a stereocontrolled manner established their absolute configurations.

引用

页码：4889 / 4904

页数：16

共 17 条

[1] SENSITIVITY-ENHANCED TWO-DIMENSIONAL HETERONUCLEAR SHIFT CORRELATION NMR-SPECTROSCOPY
BAX, A
SUBRAMANIAN, S
[J]. JOURNAL OF MAGNETIC RESONANCE, 1986, 67 (03) : 565 - 569
[2] BAX A, 1986, J AM CHEM SOC, V108, P2094
[3] ASYMMETRIC CARBON CARBON BOND FORMATION VIA BETA-ALLYLDIISOPINOCAMPHEYLBORANE - SIMPLE SYNTHESIS OF SECONDARY HOMOALLYLIC ALCOHOLS WITH EXCELLENT ENANTIOMERIC PURITIES
BROWN, HC
JADHAV, PK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (07) : 2092 - 2093
[4] 1,3-SYN DIASTEREOSELECTIVE REDUCTION OF BETA-HYDROXYKETONES UTILIZING ALKOXYDIALKYLBORANES
CHEN, KM
HARDTMANN, GE
PRASAD, K
REPIC, O
SHAPIRO, MJ
[J]. TETRAHEDRON LETTERS, 1987, 28 (02) : 155 - 158
[5] ALDEHYDES AND KETONES FROM THIOACETALS
FETIZON, M
JURION, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (07) : 382 - &
[6] GENERAL-METHOD FOR DETERMINING ABSOLUTE-CONFIGURATIONS OF ACYCLIC ALLYLIC ALCOHOLS
GONNELLA, NC
NAKANISHI, K
MARTIN, VS
SHARPLESS, KB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (13) : 3775 - 3776
[7] OXIDATION OF LONG-CHAIN AND RELATED ALCOHOLS TO CARBONYLS BY DIMETHYL-SULFOXIDE ACTIVATED BY OXALYL CHLORIDE
MANCUSO, AJ
HUANG, SL
SWERN, D
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (12) : 2480 - 2482
[8] HAPALINDOLES, ANTIBACTERIAL AND ANTIMYCOTIC ALKALOIDS FROM THE CYANOPHYTE HAPALOSIPHON-FONTINALIS
MOORE, RE
CHEUK, C
YANG, XQG
PATTERSON, GML
BONJOUKLIAN, R
SMITKA, TA
MYNDERSE, JS
FOSTER, RS
JONES, ND
SWARTZENDRUBER, JK
DEETER, JB
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (06) : 1036 - 1043
[9] ISOTACTIC POLYMETHOXY-1-ALKENES FROM BLUE-GREEN-ALGAE - SYNTHESIS AND ABSOLUTE STEREOCHEMISTRY
MORI, Y
KOHCHI, Y
SUZUKI, M
CARMELI, S
MOORE, RE
PATTERSON, GML
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (02) : 631 - 637
[10] A CONVERGENT GENERAL SYNTHETIC PROTOCOL FOR SYN-1,3-POLYOLS
MORI, Y
TAKEUCHI, A
KAGEYAMA, H
SUZUKI, M
[J]. TETRAHEDRON LETTERS, 1988, 29 (42) : 5423 - 5426

← 1 2 →