CHEMISTRY OF HETEROCYCLIC-COMPOUNDS .36. REDUCTION REACTIONS OF PYRIDYL KETONES WITH LOW VALENT TITANIUM REAGENTS

被引：29
作者：
NEWKOME, GR
ROPER, JM
机构：
[1] Department of Chemistry, Louisiana State University, Louisiana 70803, Baton Rouge
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 04期
关键词：
D O I：
10.1021/jo01318a006
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Pyridyl ketones react with low valent titanium reagents, generated either by LiAlH4 and TiCI3 or Na0 and TiCI3, to give either the corresponding alcohol or the reductively coupled products. The olefinic products generally arise when intramolecular N-complexation of the titanium ions is prevented, and ill-defined polymeric material is formed when two sites of potential complexation are available. © 1979, American Chemical Society. All rights reserved.
引用
收藏
页码：502 / 505
页数：4
相关论文
共 27 条
[1]  
BAUMSTARK AL, 1976, TETRAHEDRON LETT, P3265
[2]  
BEYERMAN HC, 1955, RECL TRAV CHIM PAY B, V74, P1395
[3]  
BOMSE DS, 1975, TETRAHEDRON LETT, P781
[4]   NEW REAGENTS FOR INTERMOLECULAR AND INTRAMOLECULAR PINACOLIC COUPLING OF KETONES AND ALDEHYDES [J].
COREY, EJ ;
DANHEISER, RL ;
CHANDRASEKARAN, S .
JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (02) :260-265
[5]   DERIVATIVES OF 1,10-PHENANTHROLINE-5,6-QUINONE [J].
DICKESON, JE ;
SUMMERS, LA .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1970, 23 (05) :1023-&
[6]   PHENANTHROLINCHINONE UND DIAZAFLUORENE [J].
DRUEY, J ;
SCHMIDT, P .
HELVETICA CHIMICA ACTA, 1950, 33 (04) :1080-1087
[7]  
ECKHARD IF, 1974, AUST J CHEM, V26, P2727
[8]   REACTIONS OF RADICAL-ANIONS .11. RADICAL-ANIONS OF SUBSTITUTED FLUORENONES [J].
EVANS, AG ;
EVANS, JC ;
EMES, PJ ;
HAIDER, SI .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1974, (10) :1121-1125
[9]  
HABERL R, 1957, MONATSH CHEM, V88, P47
[10]   Influence of poles and polar linkings on the course pursued by elimination reactions Part VI 1 1-Elimination in the degradation of quaternary ammonium hydroxides [J].
Ingold, CK ;
Jessop, JA .
JOURNAL OF THE CHEMICAL SOCIETY, 1929, :2357-2361
123