SYNTHESIS OF OPTICALLY-ACTIVE TELLURIUM-CONTAINING BINAPHTHYLS AND THEIR USE IN THE ASYMMETRIC 1,4-ADDITION REACTION OF ALPHA,BETA-UNSATURATED KETONES

被引：10

作者：

IRIE, M ^{[1
]}

DOI, Y ^{[1
]}

OHSUKA, M ^{[1
]}

ASO, Y ^{[1
]}

OTSUBO, T ^{[1
]}

OGURA, F ^{[1
]}

机构：

[1] HIROSHIMA UNIV,FAC ENGN,DEPT APPL CHEM,HIGASHIHIROSHIMA 724,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 10期

关键词：

D O I：

10.1016/S0957-4166(00)80056-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel tellurium-containing binaphthyls have been prepared in optically active form and used as chiral inducers in the asymmetric 1,4-addition reactions of alpha,beta-unsaturated ketones with aluminium arenetellurolate.

引用

页码：2127 / 2130

页数：4

共 50 条

[21] 1,4-ADDITION OF SECONDARY AND TERTIARY ALKYLZINC BROMIDES TO ALPHA,BETA-UNSATURATED KETONES WITHOUT A COPPER CATALYST
HANSON, MV
RIEKE, RD
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (43) : 10775 - 10776
[22] METAL-CATALYZED ORGANIC PHOTOREACTIONS 1,4-ADDITION OF METHANOL TO ALPHA,BETA-UNSATURATED KETONES OR ALDEHYDE
SATO, T
ITO, O
MIYAHARA, M
CHEMISTRY LETTERS, 1976, (04) : 295 - 298
[23] Stereoselective 1,4-addition of Grignard reagents to chiral gamma-alkoxy-alpha,beta-unsaturated ketones
Raczko, J
TETRAHEDRON-ASYMMETRY, 1997, 8 (22) : 3821 - 3828
[24] ORGANIC-SYNTHESIS USING HALOBORATION REACTION .16. AN ALDOL REACTION OF BORON ENOLATES GENERATED BY THE 1,4-ADDITION OF B-BR-9-BBN TO ALPHA,BETA-UNSATURATED KETONES - A SYNTHESIS OF ALPHA-BROMOMETHYL-ALPHA,BETA-UNSATURATED KETONES
SHIMIZU, H
HARA, S
SUZUKI, A
SYNTHETIC COMMUNICATIONS, 1990, 20 (04) : 549 - 555
[25] ASYMMETRIC HALOLACTONIZATION REACTION - HIGHLY EFFICIENT SYNTHESIS OF OPTICALLY-ACTIVE ALPHA-HYDROXY ACIDS FROM ALPHA,BETA-UNSATURATED ACIDS
TERASHIMA, S
JEW, S
TETRAHEDRON LETTERS, 1977, (11) : 1005 - 1008
[26] A SELECTIVE SYNTHESIS OF 3-ALKYNYL PERFLUOROALKYL KETONES BY THE TRIFLUOROBORANE ETHERATE MEDIATED 1,4-ADDITION REACTION OF (1-ALKYNYL)DIISOPROPOXYBORANES TO ALPHA,BETA-UNSATURATED KETONES
TAKADA, EI
HARA, S
SUZUKI, A
HETEROATOM CHEMISTRY, 1992, 3 (5-6) : 483 - 486
[27] A HIGHLY EFFICIENT ASYMMETRIC-SYNTHESIS OF OPTICALLY-ACTIVE ALPHA, BETA-EPOXYALDEHYDES FROM ALPHA,BETA-UNSATURATED ACIDS
TERASHIMA, S
HAYASHI, M
KOGA, K
TETRAHEDRON LETTERS, 1980, 21 (28) : 2733 - 2736
[28] Cyanuric fluoride-induced 1,4-addition reaction of alkenylboronic acids to alpha,beta-unsaturated ketones. Stereoselective synthesis of gamma,delta-unsaturated ketones having functionalities
Hara, S
Ishimura, S
Suzuki, A
SYNLETT, 1996, (10) : 993 - &
[29] 1,4-ADDITION OF RCU-ALCL3 TO ALPHA,BETA-UNSATURATED GAMMA-TERT.-BUTYLDIMETHYLSILOXY KETONES
IBUKA, T
MINAKATA, H
MITSUI, Y
KINOSHITA, K
KAWAMI, Y
KIMURA, N
TETRAHEDRON LETTERS, 1980, 21 (42) : 4073 - 4076
[30] DIASTEREOSELECTIVE 1,4-ADDITION OF ORGANOCOPPER-LANTHANOID REAGENTS TO ALPHA,BETA-UNSATURATED KETONES CONTAINING 1,3-OXATHIANE AS A CHIRAL AUXILIARY
UTIMOTO, K
KODAMA, T
MATSUBARA, S
SYNLETT, 1995, (05) : 501 - 502

← 1 2 3 4 5 →