ELECTROCHEMICAL ENHANCEMENT OF OXIDATIVE COUPLING OF METHANE OVER LiCl-DOPED NiO USING STABILIZED ZIRCONIA ELECTROLYTE

被引：41

作者：

Otsuka, Kyoshi ^{[1
]}

Suga, Katsuo ^{[1
]}

Yamanaka, Ichiro ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem Engn, Meguro Ku, Tokyo 152, Japan

来源：

CATALYSIS LETTERS | 1988年 / 1卷 / 12期

关键词：

D O I：

10.1007/BF00766201

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxidative coupling of methane into ethylene and ethane over LiCl-doped NiO was enhanced when oxygen was pumped electrochemically to the catalyst through a stabilized zirconia oxygen-anion conductor. This favourable effect can be ascribed to the generation of reactive oxygen species on the catalyst for selective synthesis of C-2 compounds.

引用

页码：423 / 428

页数：6

共 7 条

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