PHOTOCHEMICAL TRANSFORMATION OF BUFADIENOLIDE .6.

被引：0

作者：

MURAKAMI, N ^{[1
]}

TANASE, T ^{[1
]}

NAGAI, S ^{[1
]}

UEDA, T ^{[1
]}

SAKAKIBARA, J ^{[1
]}

机构：

[1] NAGOYA CITY UNIV, FAC PHARMACEUT SCI, 3-1 TANABE DORI, MIZUHO KU, NAGOYA, AICHI 467, JAPAN

来源：

CHEMICAL & PHARMACEUTICAL BULLETIN | 1991年 / 39卷 / 05期

关键词：

BUFADIENOLIDE; PROSCILLARIDIN; CARDIAC GLYCOSIDE; PHOTOLYSIS; PHOTOCHEMICAL TRANSFORMATION; METHYL 14-BETA, 21-EPOXY-21-METHOXYCHOLA-4,20(22)-DIENOATE;

D O I：

暂无

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

The photolysis of a bufadienolide glycoside, proscillaridin (1), in MeOH with a high-pressure mercury arc lamp afforded the three novel compounds (2-4) with a 14-beta,21-epoxy-21-methoxychola-4,20(22)-diene skeleton, and the known compound (5). The structures of 2, 3, and 4 were elucidated spectroscopically.

引用

页码：1330 / 1332

页数：3