CHIRAL SHIELDING IN NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY

被引：1
|
作者：
STILES, PJ
机构：
[1] School of Chemistry, Macquarie University, North Ryde, NSW
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1979年 / 32卷 / 06期
关键词：
D O I：
10.1071/CH9791375
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel van der Waals shielding mechanism is discussed which contributes to the magnetic shielding non-equivalence of optical isomers of one chiral species in the presence of a second optically active species. It is more direct than standard mechanisms which invoke stereospecific association of the interacting molecules but appears to be of marginal experimental significance. © 1979, CSIRO. All rights reserved.
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页码：1375 / 1377
页数：3
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