HYDROCARBON METAL SULPHIDE COMPLEXES .3. STEREOCHEMISTRY OF SOME RHODIUM DERIVATIVES

被引：47

作者：

BOLTON, ES

HAVLIN, R

KNOX, GR

机构：

[1] Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 18卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)80243-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparations of [RSRh(CO)2]2 (R = CH3, C6H5, p-FC6H4, C6F5) are reported, and their stereochemistry investigated. Rapid cleavage of the thio bridge by triphenylphosphine leads to complexes of the type cis-RSRh(CO) (PPh3)2. The slow isomerisation of these to the trans-isomer can be followed spectrometrically. © 1969.

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页码：153 / &

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共 25 条

[1]

AHMAD M, 1966, Z NATURFORSCH PT B, VB 21, P289

[2] HYDROCARBON METAL SULPHIDE COMPLEXES .I. CYCLOPENTADIENYLCARBONYLIRON MERCAPTIDES [J].

AHMAD, M ;

BRUCE, R ;

KNOX, GR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1966, 6 (01) :1-&

[3] DECARBONYLATION OF AROMATIC CARBONYL COMPOUNDS CATALYZED BY RHODIUM COMPLEXES [J].

BLUM, J ;

OPPENHEIMER, E ;

BERGMANN, ED .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (10) :2338-+

[4] DICARBONYL-BETA-DIKETONATO- + RELATED COMPLEXES OF RHODIUM(I) [J].

BONATI, F ;

WILKINSON, G .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (SEP) :3156-&

[5] IR SPECTROSCOPIC STUDIES OF METALLOCARBONYL COMPOUNDS .10. STUDY OF ISOMER BEHAVIOR OF SOME DI-MU-MERCAPTO-DIFERRO-HEXACARBONYLS [J].

BOR, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 11 (01) :195-&

[6] HYDROCARBON METAL SULPHIDE COMPLEXES .2. CYCLOPENTADIENYLCARBONYLIRON TRITHIOCARBONATE COMPLEXES [J].

BRUCE, R ;

KNOX, GR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1966, 6 (01) :67-&

[7] CHEMISTRY OF METAL CARBONYLS .41. SYNTHESIS OF COMPLEXES WITH C6F5S OR P-RS.C6F4 (R=ME OR PH) GROUPS AS LIGANDS [J].

COOKE, J ;

GREEN, M ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (01) :170-&

[8] DIMETHYL- + DIETHYLDITHIOCARBAMATE COMPLEXES OF SOME METAL CARBONYL COMPOUNDS [J].

COTTON, FA ;

MCCLEVERTY, JA .

INORGANIC CHEMISTRY, 1964, 3 (10) :1398-&

[9] STRUCTURE OF AND METAL-METAL BONDING IN RH(CO)2CL [J].

DAHL, LF ;

MARTELL, C ;

WAMPLER, DL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (07) :1761-&

[10] STRUCTURE AND NATURE OF BONDING OF [C2H5SFE(CO)3]2 [J].

DAHL, LF ;

WEI, CH .

INORGANIC CHEMISTRY, 1963, 2 (02) :328-&