STRUCTURE OF A C,N,N-CYCLOMETALATED PALLADIUM(II) COMPLEX OF 2-AMINO-4-PHENYLAMINO-6-(2-PYRIDYL)-1,3,5-TRIAZINE, AN ALPHA-DIIMINE LIGAND WITH DONOR-ACCEPTOR-DONOR HYDROGEN-BONDING CAPABILITY

被引:21
作者
CHAN, CW [1 ]
MINGOS, DMP [1 ]
WHITE, AJP [1 ]
WILLIAMS, DJ [1 ]
机构
[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 14期
关键词
D O I
10.1039/dt9950002469
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new class of (2,4-diamino-1,3,5-triazinyl)pyridine ligand has been made and its cyclopalladation reaction with palladium(ii) studied; the crystal structure of the C,N,N-cyclometallated complex reveals a rigid planar structure with a donor-acceptor-donor hydrogen-bonding function on its surface.
引用
收藏
页码:2469 / 2471
页数:3
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