NUCLEOPHILIC REACTIONS OF (ETA(5)C5H5)MO(CO)2(ETA(3)C6H7)

被引：0

作者：

WANG, TF

LEE, MC

WEN, YS

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 483卷 / 1-2期

关键词：

MOLYBDENUM; ALUMINUM; METAL CARBONYL CATION; ALLYLS; CYCLOPENTADIENYL;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the presence of a Lewis acid, (eta5-C5H5)Mo(CO)2(eta3-C6H7) (complex 1) reacted with aldehydes to form adducts. Proton removal by a base led to reversal of the reaction with regeneration of 1. The use of a Lewis acid such as Me3Al, which also acted as a proton scavenger, led to a smooth reaction to give 6, 7 or 8. Complex 1 also reacted with NBS to yield a complex, 9, which incorporates a succinimide group. Solid state structures of 8b and 9 were characterized by single crystal X-ray analyses.

引用

页码：91 / 97

页数：7

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