Dimethylbis(pyrazine-2-carboxylato-k(2)N(1),O)tin(IV)

被引：1
|
作者：
Vafaee, Marzieh [1 ]
Najafi, Ezzatollah [1 ]
Amini, Mostafa M. [1 ]
Ng, Seik Weng [2 ]
机构：
[1] Shahid Beheshti Univ, Dept Chem, Gen Campus, Tehran 1983963113, Iran
[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 16.6; mean ̄(C-C) = 0.003 Å; R factor = 0.020; single-crystal X-ray study; T = 295 K; wR factor = 0.051;
D O I：
10.1107/S160053681204295X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Sn(CH3)(2)(C5H3N2O2)(2)], the Sn-IV atom is twice N, O-chelated by two pyrazine-2-carboxylate ligands. The distorted six-coordination is completed by two tin-bound methyl C atoms. The C2N2O2 donor set defines a skewed trapezoidal-bipyramidal geometry. Intermolecular pi-pi inter-actions between the pyrazine rings [centroid-centroid distance = 3.8112 (13) angstrom] are observed.
引用
收藏
页码：M1384 / +
页数：6
相关论文
共 50 条
  • [41] catena-Poly[[trimethyltin(IV)]-μ-3,5-difluorobenzoato-k2O:O′]
    Liu, Hong
    Yin, Handong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1030 - U320
  • [42] Tetrakis(mu-naphthalene-1-acetatoj-k(2)O:O')bis[(N,N-dimethylformamide-kO)copper(II)]
    Yin, Fu-Jun
    Gu, Yu
    Zhao, Hong
    Bai, Di-Si
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M350 - U1076
  • [43] Poly[(mu(3)-pyridine-4-carboxylato-kappa O-3:O':N)(pyridin-1-ium-4-carboxylato-kappa O)(thiocyanato-kappa N)cobalt(II)]
    Neumann, Tristan
    Werner, Julia
    Jess, Inke
    Naether, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1435 - +
  • [44] Poly[aqua[μ3-4-carboxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxylato-κ5N1,O5:N3,O4:N2]nickel(II)]
    Jing, Xue-Min
    Gong, Shu-Zhe
    Xiao, Li-Wei
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M187 - U978
  • [45] Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ2N3,O4)magnesium(II) 3.5-hydrate
    Liu, Xiang-Yun
    Liu, Li-Hua
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M305 - U3597
  • [46] (Nitrato-κO)bis[5-(pyridin-2-yl)pyrazine-2-carbonitrile-κ2N4,N5]silver(I)
    Zhang, Fan
    Yang, Yong-Li
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1863 - U2002
  • [47] Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-k2N3:N3′](μ-5-methylisophthalato-k2O1:O3)cobalt(II)]
    Chen, Shui-Sheng
    Yang, Sen-Lin
    Zhang, Shu-Ping
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1031 - U333
  • [48] catena-Poly[[diaquabis(4-formylbenzoato-kappa O-1) nickel(II)]-mu-pyrazine-kappa N-2:N ']
    Celik, Fatih
    Dilek, Nefise
    Delibas, Nagihan Caylak
    Necefoglu, Hacali
    Hokelek, Tuncer
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M65 - +
  • [49] catena-Poly[[[cis-aquadibromidocobalt(II)]-μ-(pyrazine-2-carboxylic acid)-κ3N1,O:N4] monohydrate]
    Dares, Christopher
    Fournier, Rene
    Lever, A. B. P.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1798 - U883
  • [50] (2,2'-Bipyridine-6,6'-dicarboxylato-kappa(3) N,N',O-6)(6'-carboxy-2,2'-bipyridine6-carboxylato-kappa(3) N,N',O-6) rhodium(III)
    Wang, Huimin
    Gu, Xiaojun
    Zhang, Bingbing
    Su, Haiquan
    Hu, Ming
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M290 - U684
12345