PROTONATION STUDY AND MECHANISM OF HYDROLYSIS OF 2-[(P-METHOXYPHENYL)AZO]-1,3,4-THIADIAZOLE IN AQUEOUS SULFURIC-ACID AT 60-DEGREES-C

被引：1

作者：

OGUNJOBI, KA

机构：

[1] Department of Chemical Sciences, Ogun State University, Ago-Iwoye [Ijebu]

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 12期

关键词：

D O I：

10.1021/jo00091a028

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-[(p-Methoxyphenyl)azo]-1,3,4-thiadiazo has been found to be associated with a single protolytic equilibrium, its pK(a) value for the protonation equilibrium has been evaluated, and the structure of the protonated species has been determined. The compound hydrolyzes from the monopronated substrate by the A-S(E)2 mechanism of the SNAr type.

引用

页码：3386 / 3388

页数：3

共 8 条

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