KINETICS AND MECHANISM OF OXIDATION OF 1,4-BUTANEDIOL BY CHROMIUM(VI) IN ACID PERCHLORATE MEDIUM

被引：0
|
作者：
GUPTA, C [1 ]
MISHRA, SK [1 ]
SHARMA, PD [1 ]
机构：
[1] UNIV RAJASTHAN,DEPT CHEM,JAIPUR 302004,RAJASTHAN,INDIA
来源：
TRANSITION METAL CHEMISTRY | 1993年 / 18卷 / 03期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The kinetics of oxidation Of 1,4-butanediol by chromium(VI) was studied in acid perchlorate medium and the oxidation product of the diol was identified as 4-hydroxybutanal. The kinetic rate law observed accounted for the complex dependence of the hydrogen ion k = (k2K1[H+] + k3K1K2[H+]2)/(1 + K1[H+]) where k is the observed second-order rate constant.
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页码：299 / 303
页数：5
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