KINETICS AND MECHANISM OF OXIDATION OF 1,4-BUTANEDIOL BY CHROMIUM(VI) IN ACID PERCHLORATE MEDIUM

被引：0

作者：

GUPTA, C ^{[1
]}

MISHRA, SK ^{[1
]}

SHARMA, PD ^{[1
]}

机构：

[1] UNIV RAJASTHAN,DEPT CHEM,JAIPUR 302004,RAJASTHAN,INDIA

来源：

TRANSITION METAL CHEMISTRY | 1993年 / 18卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The kinetics of oxidation Of 1,4-butanediol by chromium(VI) was studied in acid perchlorate medium and the oxidation product of the diol was identified as 4-hydroxybutanal. The kinetic rate law observed accounted for the complex dependence of the hydrogen ion k = (k2K1[H+] + k3K1K2[H+]2)/(1 + K1[H+]) where k is the observed second-order rate constant.

引用

页码：299 / 303

页数：5

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