SYNTHESIS AND CHARACTERIZATION OF PP-G-BUTYL ACRYLATE COPOLYMERS

被引：19

作者：

SATHE, SN ^{[1
]}

SRINIVASARAO, GS ^{[1
]}

DEVI, S ^{[1
]}

机构：

[1] MAHARAJA SAYAJIRAO UNIV BARODA,FAC SCI,DEPT CHEM,BARODA 390002,GUJARAT,INDIA

来源：

POLYMER INTERNATIONAL | 1993年 / 32卷 / 03期

关键词：

BUTYL ACRYLATE; ISOTACTIC POLYPROPYLENE; PERCENT GRAFTING; GRAFTING EFFICIENCY; VISCOSITY;

D O I：

10.1002/pi.4990320304

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Butyl acrylate was grafted onto isotactic polypropylene using benzoyl peroxide as an initiator and toluene as a solvent. Effects of various parameters such as monomer and initiator concentration, reaction time and temperature on rates of polymerization, percentage grafting and grafting efficiency were studied. The extent of grafting achieved was 2-85%. The graft copolymers were characterized by IR, thermal, viscometric and contact-angle studies. Improved thermal stability and decreased intrinsic viscosity and critical surface tension were observed for graft copolymers.

引用

页码：233 / 239

页数：7

共 18 条

[1] AGRAWAL PK, 1989, POLY COMM, V30, P264
[2] CANTERON J, 1964, Patent No. 3162697
[3] NONDEGRADATIVE REACTION OF MALEIC-ANHYDRIDE AND MOLTEN POLYPROPYLENE IN THE PRESENCE OF PEROXIDES
GAYLORD, NG
MISHRA, MK
[J]. JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1983, 21 (01) : 23 - 30
[4] STUDIES ON POLYMER BLEND OF NYLON-6 AND POLYPROPYLENE OR NYLON-6 AND POLYSTYRENE USING REACTION OF POLYMER
IDE, F
HASEGAWA, A
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1974, 18 (04) : 963 - 974
[5] KLOSIEWICZ DW, 1836, Patent No. 595726
[6] MORPHOLOGY, CRYSTALLIZATION AND MELTING BEHAVIOR OF FILMS OF ISOTACTIC POLYPROPYLENE BLENDED WITH ETHYLENE PROPYLENE COPOLYMERS AND POLYISOBUTYLENE
MARTUSCELLI, E
SILVESTRE, C
ABATE, G
[J]. POLYMER, 1982, 23 (02) : 229 - 237
[7] MASAHIKO O, 1973, Patent No. 7328092
[8] GRAFTING ONTO ISOTACTIC POLYPROPYLENE .3. GAMMA-RAYS INDUCED GRAFT-COPOLYMERIZATION OF WATER-SOLUBLE VINYL MONOMERS
MEHTA, IK
KUMAR, S
CHAUHAN, GS
MISRA, BN
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1990, 41 (5-6) : 1171 - 1180
[9] GRAFT CO-POLYMERIZATION OF VINYL MONOMERS ONTO POLYPROPYLENE
MUKHERJEE, AK
GUPTA, BD
[J]. JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1983, A19 (07): : 1069 - 1099
[10] RADIATION-INDUCED GRAFT-COPOLYMERIZATION OF METHACRYLIC-ACID ONTO POLYPROPYLENE FIBERS .1. EFFECT OF SYNTHESIS CONDITIONS
MUKHERJEE, AK
GUPTA, BD
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1985, 30 (06) : 2643 - 2653

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