INFRARED-SPECTRA OF DIMETHYLPHOSPHATE LANTHANIDE COMPLEXES

被引：4

作者：

ZENG, GF ^{[1
]}

GUO, X ^{[1
]}

WANG, CY ^{[1
]}

XI, SQ ^{[1
]}

机构：

[1] ACAD SINICA,CHANGCHUN INST APPL CHEM,CHANGCHUN 130022,PEOPLES R CHINA

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1993年 / 297卷

关键词：

D O I：

10.1016/0022-2860(93)80162-O

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The infrared spectra of the crystalline solid samples of rare earth(III) dimethylphosphates Ln(DMP)3 (Ln = La, Ce, Nd) in the range 4000-100 cm-1 are discussed. It is shown that the spectra may be treated by dividing Ln(DMP)3 into two parts, an OP(OCH3)2O bridge and a LnO6 distortion octahedron. The absorption bands above 500 cm-1 may be clearly assigned. However, vibrational assignments in the far-infrared region are tentative.

引用

页码：87 / 90

页数：4

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