INFRARED-SPECTRA OF DIMETHYLPHOSPHATE LANTHANIDE COMPLEXES

被引：4
|
作者：
ZENG, GF [1 ]
GUO, X [1 ]
WANG, CY [1 ]
XI, SQ [1 ]
机构：
[1] ACAD SINICA,CHANGCHUN INST APPL CHEM,CHANGCHUN 130022,PEOPLES R CHINA
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1993年 / 297卷
关键词：
D O I：
10.1016/0022-2860(93)80162-O
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The infrared spectra of the crystalline solid samples of rare earth(III) dimethylphosphates Ln(DMP)3 (Ln = La, Ce, Nd) in the range 4000-100 cm-1 are discussed. It is shown that the spectra may be treated by dividing Ln(DMP)3 into two parts, an OP(OCH3)2O bridge and a LnO6 distortion octahedron. The absorption bands above 500 cm-1 may be clearly assigned. However, vibrational assignments in the far-infrared region are tentative.
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页码：87 / 90
页数：4
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