NATURE AND EVOLUTION OF METAMORPHIC FLUIDS ASSOCIATED WITH TURBIDITE-HOSTED GOLD DEPOSITS - HILL END GOLDFIELD, NSW, AUSTRALIA

The Hill goldfield, NSW, Australia, is an example of a syntectonic, slate-belt gold deposit formed in a multiply deformed, Late Silurian slate-metagreywacke turbidite sequence. Gold is confined to bedding-parallel veins and discordant leader veins composed of as many as four generations of quartz, accompanied by phyllosilicates, carbonates and minor sulphides. Vein formation and gold deposition was apparently synchronous with Early Carboniferous metamorphism and deformation. Homogenisation temperatures (T(h)) for fluid inclusions in vein quartz demonstrate five groupings in the temperature intervals 350-280-degrees-C, 280-250-degrees-C, 250-190-degrees-C 190-150-degrees-C, and 150-110-degrees-C, corresponding to a variety of primary and secondary inclusions developed during four periods of vein quartz deposition under a generally declining temperature regime. Inclusion fluids are characterised by a low salinity of around 0.1 to 3.6 wt.% NaCl equivalent. The dominant gas phase present in the inclusion fluids varies from N2 in the early stages of the paragenesis, through CH4 during the main episode of gold deposition, to CO2-rich fluids associated with late-stage mineralisation. DeltaO-18 values for vein quartz (range 15.1-17.1 parts per thousand) and vein carbonate (range 11.3-13.4 parts per thousand) are typical of metamorphic mineralisation. DELTAD composition of hydrous minerals and inclusion fluids (range -53 to -138 parts per thousand) suggest an influx of meteoric water in the later mineralising fluids. This conclusion is supported by deltaC-13-data for vein calcite(range -2.5 to -9.7 parts per thousand). DeltaS-34 composition of vein pyrrhotite and pyrite ranges from 6.9 to 7.8 parts per thousand early in the paragenesis, to lighter values (around 4.2 to 5.8 parts per thousand) accompanying late gold deposition from more oxidising fluids. Sulphur isotope data imply a sulphur source from underlying turbidites and an increase in fluid oxidation state during mineralisation. Lead isotope measurements on vein pyrite, arsenopyrite, galena and gold are characterised by two isotope populations with Pb-207/Pb-206 ratios of 0. 862 and 0. 860, which define two discrete mineralising events during vein formation. Consistency between data from vein minerals and lead isotope signatures for potential source rocks indicate that lead was derived from the sedimentary pile.