Crystal structure of (+/-)-1-({[4-(allyloxy)phenyl]sulfanyl}methyl)-2-(diphenylthiophosphoryl)ferrocene

被引：0

作者：

Michelot, Audric ^{[1
,2
]}

Sarda, Stephanie ^{[3
]}

Daran, Jean-Claude ^{[4
]}

Deydier, Eric ^{[1
,2
]}

Manoury, Eric ^{[1
,4
]}

机构：

[1] Univ Toulouse, UPS, INPT, F-31077 Toulouse 4, France

[2] CNRS, LCC, IUT, Dept Chim, F-81104 Castres, France

[3] Univ Toulouse 3, CIRIMAT, Equipe PPB, ENSIACET Bur 2r1 5, F-31432 Toulouse, France

[4] Lab Chim Coordinat, 205 Route Narbonne, F-31077 Toulouse 04, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; ferrocenyl ligands; planar chirality; asymmetric catalysis;

D O I：

10.1107/S2056989015013560

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Fe(C5H5)(C27H24OPS2)], is built up from a ferrocene moiety substituted in the 1- and 2-positions by {[4-(allyloxy)phenyl]sulfanyl} methyl and diphenylthiophosphoryl groups, respectively. The two S atoms lie on opposite sides of the cyclopentadienyl ring plane to which they are attached. In the crystal, C-H center dot center dot center dot S hydrogen bonds link the molecules into a ribbon running parallel to the ((1) over bar 10) plane. C-H center dot center dot center dot pi interactions link the ribbons to form a three-dimensional network.

引用

页码：972 / +

页数：11

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