POSSIBILITY OF REMARKABLE ENHANCEMENT OF SEPARATION FACTOR BY CRYOGENIC-WALL THERMAL-DIFFUSION COLUMN

From a view point that the maximum separation factor (αβ)maxattainable in total reflux operation of thermal diffusion column depends on temperature difference ΔT between hot Thand cold Tcsurfaces in the form of ΔT/Tcas where δ (≡rh/rc) is the ratio of hot wire to cold-wall radii, αTthe thermal diffusion factor and Z* (≡Z/rc) the normalized column height, remarkable enhancement of separation factor is expected through an adoption of “Cryogenic-Wall” (ex. 77.35K) instead of “Ordinary Cold- wall” (ex. Tc= 288.15K). The effect of “Cryogenic-Wall” was analyzed on the basis of approximate formulae involving explicitly design parameters for the column constants. In the case where rc=1.5 cm, Z=150 cm and ΔT=1,000 K, (αβ)maxfor H2-HT through “Ordinary Cold-wall” TD column is 63.4, while that through “Cryogenic-Wall” TD column is 885, for which ΔT= 2,430K is required in the “Ordinary Cold-wall” TD column and it is impossible for the hot-wire to be at so high temperature because of its melting. The magnitude of enhancement is, however, smaller than that expected from the ratio of ΔT/Tcbecause (1) the value of αTdecreases in lower temperature region, and (2) the argument of the exponential function for (αβ)maxis not proportional directly to αT·ΔT/Tcbut to αT·ΔT/Ŧ, where Ŧ is the reference mean temperature higher than Tc. The optimum pressure of “Cryogenic-Wall” TD column is considerably smaller (0.024 MPa for the case above) than that of “Ordinary Cold-wall” TD column (0.103 MPa). © 1990 Taylor & Francis Group, LLC.