NEAR-INFRARED ABSORPTION AND CIRCULAR DICHROISM SPECTRA OF FERROCYTOCHROME C-D-]D TRANSITIONS

被引：48

作者：

EATON, WA

CHARNEY, E

机构：

[1] Laboratory of Physical Biology, National Institute of Arthritis and Metabolic Diseases, National Institutes of Health, Bethesda

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 10期

关键词：

D O I：

10.1063/1.1671818

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transitions to the lowest crystal field singlet states of horse heart ferrocytochrome c have been identified from absorption and circular dichroism spectra in the wavelength region 5700-10 000 Å. The results are correlated with crystal field and molecular orbital theoretical predictions. The Dq value for the porphyrin ring of ferrocytochrome c is found to be between 1700 and 1900 cm-1, in excellent agreement with the extended Hückel calculations of Zerner, Gouterman, and Kobayashi.

引用

页码：4502 / &

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