SOL-GEL ROUTES LEADING TO NASICON CERAMICS

被引：50

作者：

PERTHUIS, H ^{[1
]}

COLOMBAN, P ^{[1
]}

机构：

[1] ECOLE POLYTECH,PHYS MAT CONDENSEE LAB,CHIM SOLIDE GRP,F-91128 PALAISEAU,FRANCE

来源：

CERAMICS INTERNATIONAL | 1986年 / 12卷 / 01期

关键词：

GELS; -; Synthesis;

D O I：

10.1016/S0272-8842(86)80008-6

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Nasicon and Titzicon compositions have been obtained as powders or monolithic, optically clear gels by sol-gel processes. Variations of the synthesis method have been explored by changing the proportion of metal organic reagents and the hydrolysis rate. The structural evolution as a function of temperature can be correlated with the specific area variations: the Nasicon phase is gradually formed between 800 and 1050 degree C. The target compositions were achieved with only a small Zr deficiency.

引用

页码：39 / 52

页数：14