ELECTRON PARAMAGNETIC RESONANCE OF PU3+ IN CUBIC SYMMETRY SITES IN CAF2, SRF2, AND BAF2

被引：28

作者：

EDELSTEIN, N

MOLLET, HF

EASLEY, WC

MEHLHORN, RJ

机构：

[1] Lawrence Radialion Laboratory, University of California, Berkeley

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 08期

关键词：

D O I：

10.1063/1.1672508

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The g values of the ground FT state of Pua+ in cubic symmetry sites in CaF2, SrF2, and BaF2 are 1.297± 0.001, 1.250±0.002, and 1.187±0004, respectively, as measured at r=1.2°K by EPR techniques. By fitting the g values, estimates of the crystalline-field parameters are derived. It is shown that crystallinefield effects for Pu3+ in the alkaline-earth fluorides are the same order of magnitude as in the lanthanide series.

引用

页码：3281 / +

页数：1

共 14 条

[1] CRYSTAL FIELDS AT RARE-EARTH IONS [J].