INTERACTION OF HYDROGEN WITH COPPER CHROMITE SURFACE

被引：13

作者：

KHASIN, AV

SIMENTSOVA, II

YURIEVA, TM

机构：

[1] Boreskov Institute of Catalysis, SB of RAS, Novosibirsk

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1994年 / 52卷 / 01期

关键词：

D O I：

10.1007/BF02129858

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Kinetics of the surface reduction of copper chromite, CuCr2O4, with molecular hydrogen has been studied. H-2 transformation proceeds with participation of copper reduced states, probably Cu-degrees, formed as a result of surface reaction. Process kinetics has a topochemical character. Reaction rate as a function of surface reduction degree, x, reaches a maximum near x=0.5.

引用

页码：113 / 118

页数：6

共 4 条

[1] APAI G, 1984, APPL SURF SCI, V19, P307
[2] RELATIONSHIP BETWEEN STABLE MONO-VALENT COPPER IN COPPER CHROMIA CATALYSTS AND ACTIVITY FOR METHANOL FORMATION
APAI, GR
MONNIER, JR
HANRAHAN, MJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (04) : 212 - 213
[3] STRUCTURE OF CATALYTIC SITES ON HYDROGEN-TREATED COPPER-CONTAINING SPINEL CATALYSTS
JALOWIECKI, L
WROBEL, G
DAAGE, M
BONNELLE, JP
[J]. JOURNAL OF CATALYSIS, 1987, 107 (02) : 375 - 392
[4] MAKAROVA OV, 1993, KINET KATAL, V34, P681

← 1 →