UNEXPECTED REGIOSELECTIVE SYNTHESIS OF 1,1-DIPHOSPHINOETHANES AND RELATED-COMPOUNDS VIA HYDROZIRCONATION OF VINYLPHOSPHINES

被引：23
|
作者：
ZABLOCKA, M
IGAU, A
MAJORAL, JP
PIETRUSIEWICZ, KM
机构：
[1] CNRS, CHIM COORDINAT LAB, 205 ROUTE NARBONNE, F-31077 TOULOUSE, FRANCE
[2] POLISH ACAD SCI, CTR MOLEC & MACROMOLEC STUDIES, PL-90363 LODZ, POLAND
来源：
ORGANOMETALLICS | 1993年 / 12卷 / 03期
关键词：
D O I：
10.1021/om00027a004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hydrozirconation of vinylphosphines, R2-PCH-CH2, and the corresponding phosphine oxides and sulfides, followed by addition of chlorodiphenylphosphine, led to the 1,1-diphosphinoethanes R2P(X)CH-(CH3)PPh2 (X = lone pair, O, S). Hydrozirconation of phospholene oxides 16 and 17 gave selectively the corresponding phospholene 18 and then the phospholane 19.
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页码：603 / 604
页数：2
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