UNEXPECTED REGIOSELECTIVE SYNTHESIS OF 1,1-DIPHOSPHINOETHANES AND RELATED-COMPOUNDS VIA HYDROZIRCONATION OF VINYLPHOSPHINES

被引：23

作者：

ZABLOCKA, M

IGAU, A

MAJORAL, JP

PIETRUSIEWICZ, KM

机构：

[1] CNRS, CHIM COORDINAT LAB, 205 ROUTE NARBONNE, F-31077 TOULOUSE, FRANCE

[2] POLISH ACAD SCI, CTR MOLEC & MACROMOLEC STUDIES, PL-90363 LODZ, POLAND

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 03期

关键词：

D O I：

10.1021/om00027a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrozirconation of vinylphosphines, R2-PCH-CH2, and the corresponding phosphine oxides and sulfides, followed by addition of chlorodiphenylphosphine, led to the 1,1-diphosphinoethanes R2P(X)CH-(CH3)PPh2 (X = lone pair, O, S). Hydrozirconation of phospholene oxides 16 and 17 gave selectively the corresponding phospholene 18 and then the phospholane 19.

引用

页码：603 / 604

页数：2

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