UNEXPECTED REGIOSELECTIVE SYNTHESIS OF 1,1-DIPHOSPHINOETHANES AND RELATED-COMPOUNDS VIA HYDROZIRCONATION OF VINYLPHOSPHINES

被引：23
|
作者：
ZABLOCKA, M
IGAU, A
MAJORAL, JP
PIETRUSIEWICZ, KM
机构：
[1] CNRS, CHIM COORDINAT LAB, 205 ROUTE NARBONNE, F-31077 TOULOUSE, FRANCE
[2] POLISH ACAD SCI, CTR MOLEC & MACROMOLEC STUDIES, PL-90363 LODZ, POLAND
来源：
ORGANOMETALLICS | 1993年 / 12卷 / 03期
关键词：
D O I：
10.1021/om00027a004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hydrozirconation of vinylphosphines, R2-PCH-CH2, and the corresponding phosphine oxides and sulfides, followed by addition of chlorodiphenylphosphine, led to the 1,1-diphosphinoethanes R2P(X)CH-(CH3)PPh2 (X = lone pair, O, S). Hydrozirconation of phospholene oxides 16 and 17 gave selectively the corresponding phospholene 18 and then the phospholane 19.
引用
收藏
页码：603 / 604
页数：2
相关论文
共 50 条
  • [1] SYNTHESIS OF 1,1-DIMETHYLCARBAPENEM DERIVATIVES AND RELATED-COMPOUNDS
    SHIBUYA, M
    INOUE, T
    JINBO, Y
    KUBOTA, S
    HETEROCYCLES, 1982, 19 (01) : 188 - 188
  • [2] 1,1'-DIMESITYLURANOCENE AND RELATED-COMPOUNDS
    STREITWIESER, A
    WANG, HK
    LYTTLE, M
    SOLAR, JP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 180 (AUG): : 185 - ORGN
  • [3] SYNTHESIS AND ANTI-HIV ACTIVITY OF 1,1'-DIDEOXYGOSSYPOL AND RELATED-COMPOUNDS
    ROYER, RE
    DECK, LM
    VANDERJAGT, TJ
    MARTINEZ, FJ
    MILLS, RG
    YOUNG, SA
    VANDERJAGT, DL
    JOURNAL OF MEDICINAL CHEMISTRY, 1995, 38 (13) : 2427 - 2432
  • [4] SYNTHESIS OF ISOTOPICALLY LABELED 1,1'-THIOBIS(2-CHLOROETHANE) AND SOME RELATED-COMPOUNDS
    HARRISON, JM
    JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS, 1991, 29 (10): : 1175 - 1180
  • [5] REGIOSELECTIVE SYNTHESIS OF PRENYLISOFLAVONES - SYNTHESES OF 2,3-DEHYDROKIEVITONE AND RELATED-COMPOUNDS
    TSUKAYAMA, M
    TSURUMOTO, K
    KISHIMOTO, K
    HIGUCHI, D
    CHEMISTRY LETTERS, 1994, (11) : 2101 - 2104
  • [6] SYNTHESIS OF 1-ISOCYANOMETHYL AZOLES AND RELATED-COMPOUNDS
    SAIKACHI, H
    SASAKI, H
    KITAGAWA, T
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1983, 31 (02) : 723 - 726
  • [7] NMR SPECTROSCOPICAL INVESTIGATIONS OF THIOPHENE 1,1-DIOXIDE AND RELATED-COMPOUNDS
    MEIER, H
    MOLZ, T
    KOLSHORN, H
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1984, 39 (07): : 915 - 920
  • [8] SYNTHESIS OF 1-BENZOTHIOPYRYLIUM PERCHLORATES AND RELATED-COMPOUNDS
    NAKAZUMI, H
    KITAO, T
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (08) : 2415 - 2416
  • [9] SYNTHESIS OF 1-BENZOYLPYRROLINE DERIVATIVE AND RELATED-COMPOUNDS
    ELBANNANY, AAA
    IBRAHIM, LI
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1989, 44 (02): : 233 - 236
  • [10] SYNTHESIS OF SOME NUCLEOSIDE CYCLIC PHOSPHORAMIDATES AND RELATED-COMPOUNDS VIA PHOSPHORAMIDITES
    JONES, AS
    MCGUIGAN, C
    WALKER, RT
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1985, (02): : 199 - 202
12345