MOLECULAR-DYNAMICS OF ANTIMONY-TRICHLORIDE IN CRYSTALS OF BIMOLECULAR MENSHUTKIN COMPLEXES WITH BENZENE, DIPHENYL AND PHENANTHRENE BY RAMAN-SPECTROSCOPY

被引:8
|
作者
KONDYURIN, AV
MIKOV, SN
KOZULIN, AT
机构
[1] ULYANOVSK MICROELECTR CTR,ULYANOVSK 432700,USSR
[2] MV LOMONOSOV STATE UNIV,ULYANOVSK 432700,USSR
关键词
D O I
10.1002/jrs.1250220502
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The Raman spectra of bimolecular complexes crystals of antimony trichloride with benzene, diphenyl and phenanthrene were studied at 77 K. A group theoretical analysis and normal coordinates analysis of the antimony trichloride vibrations in complexes was made. The variation of force field with the gas-crystal phase change parameters of intermolecular interaction was defined. The interpretation of the lattice mode region was accomplished.
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页码:249 / 252
页数:4
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