ASYMPTOTIC FORM OF QUANTUM MOMENTUM DISTRIBUTIONS

被引:4
作者
BERMAN, DH
SNIDER, RF
机构
[1] Department of Chemistry, University of British Columbia, Vancouver
关键词
D O I
10.1063/1.438525
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The behavior at large momentum, of the first density correction to the momentum distribution of a gas of interacting particles, is investigated for a wide variety of model potentials. The treatment involves neither an expansion in powers of the potential strength Vo nor of Planck's constant ℏ. As well, the results are valid for all temperatures and include exchange effects. It is shown that slow algebraic decay of the momentum distribution is not peculiar to hard sphere interactions, but also occurs for such smooth interactions as the Yukawa and exponential potential, whose momentum distributions decay as p-8 and p-12, respectively. The pseudopotential gives rise to a p-4 decay, in contrast to the p -6 decay for the hard sphere interaction which it is designed to model. For singular potentials of the form Vo(a/r)n, a lower bound is obtained which has (almost) exponential decay. © 1979 American Institute of Physics.
引用
收藏
页码:1740 / 1753
页数:14
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