A NEW MO5+ PHOSPHATE WITH A TUNNEL STRUCTURE - GAMMA-CSMO2P3O13

被引：27
|
作者：
CHEN, JJ
LII, KH
WANG, SL
机构：
[1] ACAD SINICA,INST CHEM,TAIPEI 115,TAIWAN
[2] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 300,TAIWAN
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 1988年 / 76卷 / 01期
关键词：
Cesium Compounds--Structure - Crystals--Structure;
D O I：
10.1016/0022-4596(88)90208-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Mo5+ phosphate, γ-CsMo2P3O13, was discovered and its crystal structure was determined from single-crystal X-ray diffraction data. The structure consists of three different tunnels of which the large and medium ones are occupied by cesium cations. The framework is built up from MoO6 octahedra, PO4 tetrahedra, and P2O7 groups. The γ-CsMo2P3O13 structure is closely related to that of the β-form.
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页码：204 / 209
页数：6
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