OXIDATION OF MILD AND LOW-ALLOY STEELS IN CO2 BASED ATMOSPHERES

被引：49

作者：

ANTILL, JE

PEAKALL, KA

WARBURTON, JB

机构：

[1] Metallurgy Division, A.E.R.E., Didcot, Berks. England

来源：

CORROSION SCIENCE | 1968年 / 8卷 / 09期

关键词：

D O I：

10.1016/S0010-938X(68)80103-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The behaviour of pure Fe, a rimming steel and three low-alloy steels has been fully characterized in CO2 containing small amounts of CO and H2O at 500 °C. Emphasis has been given to the provision of basic data to assist in the identification of the mechanisms responsible for the formation of non-protective oxide together with linear oxidation rates. Essential conditions for non-protective oxidation are the presence of water vapour and a high pressure of CO2. The adverse influence of water vapour is enhanced by deposits of Au, C, and Pt on the metal. C may be transferred from the gas phase as several per cent of the O transfer by the Boudouard or a similar reaction, utilizing CO produced by prior oxidation of the metal with CO2. Two tentative mechanisms are advanced to explain non-protective oxidation. © 1968.

引用

页码：689 / +

页数：1

共 7 条

[1]

ANTILL JE, 1964, 3 P GEN C PEAC US AT, V9, P523

[2] IDENTIFICATION OF THE DIFFUSION OF IRON IONS IN MAGNETITE EMPLOYING MARKERS [J].