SOLVENT DEPENDENT HYPER-POLARIZABILITY OF A MEROCYANINE DYE

被引:73
作者
LEVINE, BF
BETHEA, CG
WASSERMAN, E
LEENDERS, L
机构
[1] Bell Laboratories, Murray Hill
[2] Allied Chemical, Morristown
[3] Afga-Gevaert, Antwerp
关键词
D O I
10.1063/1.435620
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The second order hyperpolarizability β of a highly solvent sensitive merocyanine dye has been measured in both polar and nonpolar solvents. A theory is developed which accounts for both the magnitude as well as the unusual negative absolute sign of β. © 1978 American Institute of Physics.
引用
收藏
页码:5042 / 5045
页数:4
相关论文
共 22 条
[1]   COLOR AND CONSTITUTION .11. ANHYDRONIUM BASES OF PARA-HYDROXYSTYRYL DYES AS SOLVENT POLARITY INDICATORS [J].
BROOKER, LGS ;
KEYES, GH ;
HESELTINE, DW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (11) :5350-5356
[2]   CONJUGATED ELECTRON CONTRIBUTIONS TO SECOND-ORDER HYPERPOLARIZABILITY OF SUBSTITUTED BENZENE MOLECULES [J].
LEVINE, BF .
JOURNAL OF CHEMICAL PHYSICS, 1975, 63 (01) :115-117
[3]   DONOR-ACCEPTOR CHARGE-TRANSFER CONTRIBUTIONS TO 2ND ORDER HYPERPOLARIZABILITY [J].
LEVINE, BF .
CHEMICAL PHYSICS LETTERS, 1976, 37 (03) :516-520
[4]   2ND AND 3RD ORDER HYPERPOLARIZABILITIES OF ORGANIC-MOLECULES [J].
LEVINE, BF ;
BETHEA, CG .
JOURNAL OF CHEMICAL PHYSICS, 1975, 63 (06) :2666-2682
[5]   HYPERPOLARIZABILITY OF PYRIDINE-IODINE CHARGE-TRANSFER COMPLEX [J].
LEVINE, BF ;
BETHEA, CG .
JOURNAL OF CHEMICAL PHYSICS, 1976, 65 (06) :2439-2442
[6]   CHARGE-TRANSFER COMPLEXES AND HYPERPOLARIZABILITIES [J].
LEVINE, BF ;
BETHEA, CG .
JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (03) :1070-1074
[7]   BOND-CHARGE CALCULATION OF NONLINEAR OPTICAL SUSCEPTIBILITIES FOR VARIOUS CRYSTAL-STRUCTURES [J].
LEVINE, BF .
PHYSICAL REVIEW B, 1973, 7 (06) :2600-2626
[8]  
LEVINE BF, UNPUBLISHED
[9]  
LEVINE BF, 1977, DIELECTRIC RELATED P, V3
[10]  
LIPTAY W, 1968, Z NATURFORSCH PT A, VA 23, P1613