THE SYNTHESIS AND CRYSTAL-STRUCTURES OF THE TETRAPHENYLARSONIUM SALTS OF [V2O3(NO3)(2)X(4)](2-),X=CL OR NO3

被引：3
|
作者：
ARROWSMITH, S
DOVE, MFA
GIBBONS, MN
LOGAN, N
BATSANOV, A
机构：
[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND
[2] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 17期
关键词：
D O I：
10.1039/c39950001733
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compounds, [Ph(4)As](2)[V2O3(NO3)(6)] 1, and [Ph(4)As](2)[V2O3Cl4(NO3)(2)] 2, crystallised from solution in the reaction of tetraphenylarsonium nitrate with VO(NO3)3 and VOCl3, respectively, and the crystal structures of the dianions show that they are structurally related; the octahedral coo rdination of all vanadium atoms is achieved by two oxygens, a bidentate nitrate and two other monodentate groups, and an unusual feature of compound 2 is the presence of both chlorine and nitrate as ligands on vanadium(v).
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收藏
页码：1733 / 1734
页数：2
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