Trichlorido(5,5'-dimethyl-2,2'-bipyridine-kappa N-2,N')(dimethylformamide-kappa O)-indium(III) hemihydrate

被引：2

作者：

Shirvan, Sadif A. ^{[1
]}

Dezfuli, Sara Haydari ^{[1
]}

Khazali, Fereydoon ^{[1
]}

Aghajeri, Manouchehr ^{[1
]}

Borsalani, Ali ^{[2
]}

机构：

[1] Islamic Azad Univ, Dept Chem, Omidieh Branch, Omidieh, Iran

[2] Islamic Azad Univ, Dept Petr Engn, Omidieh Branch, Omidieh, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 17.2; mean ω(C-C) = 0.005 Å; R factor = 0.034; single-crystal X-ray study; T = 173 K; wR factor = 0.067;

D O I：

10.1107/S1600536812044698

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]center dot 0.5H(2)O, contains two independent In III complex molecules with similar structures and one lattice water molecule. In each complex molecule, the In III atom is six-coordinated in a distorted octahedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethylformamide and three facial Cl atoms. In the crystal, the lattice water molecule is linked to the complex molecules via O-H center dot center dot center dot Cl hydrogen bonds. Further weak C-H center dot center dot center dot Cl and C-H center dot center dot center dot O hydrogen bonds result in the formation of a three-dimensional structure.

引用

页码：M1448 / +

页数：13

共 11 条

[1]

Albada G. A. V., 2004, EUR J INORG CHEM, P3733

[2] Synthesis, characterization, and crystal structure determination of two mercury(II) dimer complexes with 4,7-diphenyl-1,10-phenanthroline, 5,5'-dimethyl-2,2'-bipyridine and bromide [J].

Alizadeh, Robabeh ;

Amani, Vahid ;

Farshady, Ali Akbar ;

Khavasi, Hamid Reza .

JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (12) :2122-2131

[3] Synthesis, characterization and crystal structure determination of iron(III) hetero-ligand complexes containing 2,2′-bipyridine, 5,5′-dimethyl-2,2′-bipyridine and chloride, [Fe(bipy)Cl4][bipy•H] and [Fe(dmbipy)2Cl2][FeCl4] [J].

Amani, Vahid ;

Safari, Nasser ;

Khavasi, Hamid Reza .

POLYHEDRON, 2007, 26 (15) :4257-4262

[4] Synthesis, characterization and crystal structure determination of platinum(IV) complexes containing, bipyridine derivatives and chloride, [Pt(5,5′-dmbipy)Cl4] and [Pt(6-mbipy)Cl4] [J].

Amani, Vahid ;

Safari, Nasser ;

Khavasi, Hamid Reza ;

Akkurt, Mehmet .

POLYHEDRON, 2009, 28 (14) :3026-3030

[5]

Bruker, 2007, APEX2 SAINT

[6]

Bruker, 2001, SADABS

[7] Trichlorido(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)(methanol-κO)indium(III) [J].

Kalateh, Khadijeh ;

Ahmadi, Roya ;

Ebadi, Amin ;

Amani, Vahid ;

Khavasi, Hamid Reza .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1353-U75

[8] Dichlorido(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)zinc(II) [J].

Khalighi, Aida ;

Ahmadi, Roya ;

Amani, Vahid ;

Khavasi, Hamid Reza .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1211-U994

[9] (5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)diiodidomercury(II) [J].

Pour, Nasim Tadayon ;

Ebadi, Amin ;

Abedi, Anita ;

Amani, Vahid ;

Khavasi, Hamid Reza .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1305-U769

[10] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

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