Trichlorido(5,5'-dimethyl-2,2'-bipyridine-kappa N-2,N')(dimethylformamide-kappa O)-indium(III) hemihydrate

被引：2

作者：

Shirvan, Sadif A. ^{[1
]}

Dezfuli, Sara Haydari ^{[1
]}

Khazali, Fereydoon ^{[1
]}

Aghajeri, Manouchehr ^{[1
]}

Borsalani, Ali ^{[2
]}

机构：

[1] Islamic Azad Univ, Dept Chem, Omidieh Branch, Omidieh, Iran

[2] Islamic Azad Univ, Dept Petr Engn, Omidieh Branch, Omidieh, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 17.2; mean ω(C-C) = 0.005 Å; R factor = 0.034; single-crystal X-ray study; T = 173 K; wR factor = 0.067;

D O I：

10.1107/S1600536812044698

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]center dot 0.5H(2)O, contains two independent In III complex molecules with similar structures and one lattice water molecule. In each complex molecule, the In III atom is six-coordinated in a distorted octahedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethylformamide and three facial Cl atoms. In the crystal, the lattice water molecule is linked to the complex molecules via O-H center dot center dot center dot Cl hydrogen bonds. Further weak C-H center dot center dot center dot Cl and C-H center dot center dot center dot O hydrogen bonds result in the formation of a three-dimensional structure.

引用

页码：M1448 / +

页数：13

共 50 条

[1] (4,4 '-Dimethyl-2,2 '-bipyridine-kappa N-2,N ')(dimethylformamide-kappa O)diiodidocadmium
Shirvan, Sadif A.
Dezfuli, Sara Haydari
Khazali, Fereydoon
Borsalani, Ali
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1495 - +
[2] Trichlorido(4,4'-dimethyl-2,2'-bipyridine-kappa N-2, N')(methanol-kappa O) indium(III) methanol monosolvate
Shirvan, Sadif A.
Dezfuli, Sara Haydari
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1189 - +
[3] Trichlorido(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)(methanol-κO)indium(III)
Kalateh, Khadijeh
Ahmadi, Roya
Ebadi, Amin
Amani, Vahid
Khavasi, Hamid Reza
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1353 - U75
[4] catena-Poly[[(5,5 '-dimethyl-2,2 '-bipyridine-kappa N-2,N ')cadmium]-di-mu-bromido]
Shirvan, Sadif A.
Dezfuli, Sara Haydari
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M846 - +
[5] Dibromido(4,4 '-dimethyl-2,2 '-bipyridine-kappa N-2,N')(dimethyl sulfoxide-kappa O)-cadmium
Shirvan, Sadif A.
Dezfuli, Sara Haydari
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1006 - +
[6] Bis(acetato-kappa O-2,O ')(4,4 '-dimethyl-2,2 '-bipyridine-kappa N-2,N ')zinc
Harvey, Miguel A.
Suarez, Sebastian A.
Ibanez, Andres
Doctorovich, Fabio
Baggio, Ricardo
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1377 - +
[7] (Carbonato-kappa O-2,O ')bis(5,5 '-dimethyl-2,2 '-bipyridyl-kappa N-2,N ')cobalt(III) bromide trihydrate
Kumar, Kannan Arun
Meera, Parthsarathi
Selvi, Madhavan Amutha
Dayalan, Arunachalam
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M383 - +
[8] Dibromido(6,6'-dimethyl-2,2'-bipyridine-kappa N-2,N')cobalt(II)
Shirvan, Sadif A.
Dezfuli, Sara Haydari
Khazali, Fereydoon
Aghajeri, Manouchehr
Borsalani, Ali
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1363 - +
[9] Trichlorido(dimethyl sulfoxide-kappa O)(di-2-pyridylamine-kappa N-2,N ')indium(III)
Shirvan, Sadif A.
Dezfuli, Sara Haydari
Golabi, Elyas
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1256 - +
[10] Tetraethylammonium trichlorido(N, N' dimethylformamide-kappa O) zinc
Chao, Guo-Ping
Shi, Hua-Tian
Chen, Qun
Zhang, Qian-Feng
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M344 - +

← 1 2 3 4 5 →