DIFFUSION-COEFFICIENTS IN AQUEOUS-SOLUTIONS OF BERYLLIUM SULFATE AT 298-K

被引:19
|
作者
LOBO, VM
RIBEIRO, ACF
VERISSIMO, LM
机构
[1] Department of Chemistry, University of Coimbra
来源
关键词
Beryllium sulfate - Onsager Fuoss treatment - Pikai theory;
D O I
10.1021/je00016a020
中图分类号
O414.1 [热力学];
学科分类号
摘要
Differential diffusion coefficients of beryllium sulfate in water at 298 K and at different concentrations have been measured using a conductimetric cell. The results are discussed on the basis of the Onsager-Fuoss theory. The results were interpreted with success, using the developments introduced by Pikal in the above theory. The cell uses an open-ended capillary method, and a conductimetric technique is used to follow the diffusion process by measuring the resistance of a solution inside the capillaries at recorded times.
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页码:726 / 728
页数:3
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