TRANSITION-METAL SACCHARIDE CHEMISTRY - D-GLUCOSE COMPLEXES OF MN(II), CO(II), NI(II), CU(II) AND ZN(II)

被引：0

作者：

BANDWAR, RP ^{[1
]}

RAGHAVAN, MSS ^{[1
]}

RAO, CP ^{[1
]}

机构：

[1] INDIAN INST TECHNOL, DEPT CHEM, BIOINORGAN LAB, BOMBAY 400076, MAHARASHTRA, INDIA

来源：

BIOMETALS | 1995年 / 8卷 / 01期

关键词：

CO(II); COMPLEXES; CU(II); GLUCOSE; MN(II); NI(II); SACCHARIDE; TRANSITION METAL; ZN(II);

D O I：

暂无

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Metal complexes of D-glucose (D-Glc) from large cation containing dibromo-dichloro salts of dipositive metals [NEt(4)](2)[MBr(2)Cl(2)] (M = Mn, Co, Ni, Cu and Zn) and the disodium salt of glucose were synthesized from a MeOH:MeCN mixture. The complexes were characterized by UV-vis absorption, circular dichroism, IR and proton magnetic resonance spectroscopies, and by elemental analysis, and were found to be Na[M(D-Glc)(OMe)Cl]. Cyclic voltammetric studies of these complexes, in the acidic to neutral pH range, indicated no dissociation, even in highly acidic conditions.

引用

页码：19 / 24

页数：6

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