TRANSITION-METAL SACCHARIDE CHEMISTRY - D-GLUCOSE COMPLEXES OF MN(II), CO(II), NI(II), CU(II) AND ZN(II)

被引：0
|
作者：
BANDWAR, RP [1 ]
RAGHAVAN, MSS [1 ]
RAO, CP [1 ]
机构：
[1] INDIAN INST TECHNOL, DEPT CHEM, BIOINORGAN LAB, BOMBAY 400076, MAHARASHTRA, INDIA
来源：
BIOMETALS | 1995年 / 8卷 / 01期
关键词：
CO(II); COMPLEXES; CU(II); GLUCOSE; MN(II); NI(II); SACCHARIDE; TRANSITION METAL; ZN(II);
D O I：
暂无
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Metal complexes of D-glucose (D-Glc) from large cation containing dibromo-dichloro salts of dipositive metals [NEt(4)](2)[MBr(2)Cl(2)] (M = Mn, Co, Ni, Cu and Zn) and the disodium salt of glucose were synthesized from a MeOH:MeCN mixture. The complexes were characterized by UV-vis absorption, circular dichroism, IR and proton magnetic resonance spectroscopies, and by elemental analysis, and were found to be Na[M(D-Glc)(OMe)Cl]. Cyclic voltammetric studies of these complexes, in the acidic to neutral pH range, indicated no dissociation, even in highly acidic conditions.
引用
收藏
页码：19 / 24
页数：6
相关论文
共 50 条
  • [1] Synthesis, characterization and antimicrobial study of polymeric transition metal complexes of,Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)
    Khan, Shamim Ahmad
    Nami, Shahab A. A.
    Bhat, Shahnawaz Ahmad
    Kareem, Abdul
    Nishat, Nahid
    MICROBIAL PATHOGENESIS, 2017, 110 : 414 - 425
  • [2] COMPLEXES OF SUBSTITUTED SALICYLALDEHYDES WITH CU(II), NI(II), CO(II), ZN(II) AND MN(II)
    RATOLIKAR, VG
    JAHAGIRDAR, DV
    KHANOLKAR, DD
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1978, 16 (06): : 510 - 513
  • [3] MN(II), CO(II), NI(II), CU(II), ZN(II) AND CD(II) COMPLEXES OF ACRYLAMIDE
    SAMANTARAY, A
    PANDA, PK
    MOHAPATRA, BK
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1980, 57 (04) : 430 - 432
  • [4] COMPLEXES OF 1-HYDROXYXANTHONE WITH CU(II), NI(II), CO(II), MN(II), ZN(II) AND MG(II)
    DANGALLA, ACM
    DIAS, HW
    ILEPERUMA, OA
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1986, 25 (01): : 80 - 81
  • [5] COMPLEXES OF BENZOYLISONICOTINIC ACID HYDRAZIDE WITH VO(II), MN(II), CO(II), NI(II), CU(II) AND ZN(II)
    AGGARWAL, RC
    SINGH, NK
    PRASAD, L
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1976, 14 (03): : 181 - 183
  • [6] Synthesis and characterization of metal complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with tetradentate Schiff bases
    Liu, JN
    Wu, BW
    Zhang, B
    Liu, YC
    TURKISH JOURNAL OF CHEMISTRY, 2006, 30 (01) : 41 - 48
  • [7] Co(II), Ni(II), Cu(II) and Zn(II) complexes of thiosemicarbazones
    Chandra, S
    Gupta, L
    Tyagi, VP
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1996, 26 (01): : 125 - 137
  • [8] Co(II), Ni(II), Cu(II) and Zn(II) complexes of tetraphenylazadipyrromethene
    Palma, Aniello
    Gallagher, John F.
    Mueller-Bunz, Helge
    Wolowska, Joanna
    McInnes, Eric J. L.
    O'Shea, Donal F.
    DALTON TRANSACTIONS, 2009, (02) : 273 - 279
  • [9] Co(II), Ni(II), Cu(II), and Zn(II) Complexes of Thiosemicarbazones
    Chandra, S.
    Gupta, L.
    Tyagi, V. P.
    Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 26 (01):
  • [10] Synthesis and characterization of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) azo coumarin complexes
    Hankare, PP
    Naravane, SR
    Bhuse, VM
    Delekar, SD
    Jagtap, AH
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2004, 43 (07): : 1464 - 1467
12345