THE CHIRAL AMINO ALCOHOL, CIS-2-AMINO-1-ACENAPHTHENOL - SYNTHESIS, RESOLUTION, AND APPLICATION TO THE DIASTEREOSELECTIVE [2,3]-WITTIG REARRANGEMENT

被引：16
|
作者：
SUDO, A [1 ]
HASHIMOTO, Y [1 ]
KIMOTO, H [1 ]
HAYASHI, K [1 ]
SAIGO, K [1 ]
机构：
[1] UNIV TOKYO,FAC ENGN,DEPT CHEM & BIOTECHNOL,BUNKYO KU,TOKYO 113,JAPAN
来源：
TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 07期
关键词：
D O I：
10.1016/0957-4166(94)80175-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The chiral amino alcohol, cis-2-amino-1-acenaphthenol, was synthesized, and resolved by a simple procedure. This new chiral amino alcohol was converted into an oxazoline derivative and applied as a chiral auxiliary to the diastereoselective [2,3]-Wittig rearrangement.
引用
收藏
页码：1333 / 1346
页数：14
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