THE CHIRAL AMINO ALCOHOL, CIS-2-AMINO-1-ACENAPHTHENOL - SYNTHESIS, RESOLUTION, AND APPLICATION TO THE DIASTEREOSELECTIVE [2,3]-WITTIG REARRANGEMENT

被引：16

作者：

SUDO, A ^{[1
]}

HASHIMOTO, Y ^{[1
]}

KIMOTO, H ^{[1
]}

HAYASHI, K ^{[1
]}

SAIGO, K ^{[1
]}

机构：

[1] UNIV TOKYO,FAC ENGN,DEPT CHEM & BIOTECHNOL,BUNKYO KU,TOKYO 113,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 07期

关键词：

D O I：

10.1016/0957-4166(94)80175-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chiral amino alcohol, cis-2-amino-1-acenaphthenol, was synthesized, and resolved by a simple procedure. This new chiral amino alcohol was converted into an oxazoline derivative and applied as a chiral auxiliary to the diastereoselective [2,3]-Wittig rearrangement.

引用

页码：1333 / 1346

页数：14

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