DEGENERATE ELECTRON EXCHANGE OF RADICAL IONS IN LIQUID SOLUTION STUDIED BY PULSE NMR

被引：14

作者：

BURRI, J

FISCHER, H

机构：

[1] Physikalisch-Chemisches Institut der Universität Zürich

来源：

CHEMICAL PHYSICS | 1992年 / 161卷 / 03期

关键词：

D O I：

10.1016/0301-0104(92)80158-R

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Simple H-1-NMR pulse sequences on the mu-s to ms time scale are presented to study the kinetics of the reversible electron exchange of radical anions and cations after their pulsed optical formation in solution. Measurements on the system anthracene and N,N-dimethyl-p-toluidine yield rate constants for the electron transfer and for the kinetics of irreversible radical ion decay processes.

引用

页码：429 / 435

页数：7

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