ION-EXCHANGE OF FE-3+ IN ZSM-5

被引：18

作者：

KALIAGUINE, S

LEMAY, G

ADNOT, A

BURELLE, S

AUDET, R

JEAN, G

SAWICKI, JA

机构：

[1] CANADA CTR MINERAL & ENERGY TECHNOL,ENERGY RES LABS,OTTAWA,ONTARIO,CANADA

[2] CHALK RIVER NUCL LABS,CHALK RIVER,ONTARIO,CANADA

来源：

ZEOLITES | 1990年 / 10卷 / 06期

关键词：

Ion-exchange Fe[!sup]3+[!/sup] in Na-ZSM-5; reduction Fe[!sup]3+[!/sup] to Fe[!sup]2+[!/sup; t.p.r. of Fe[!sup]2+[!/sup] HZSM-5;

D O I：

10.1016/S0144-2449(05)80312-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ion exchange of Fe3+ with sodium in NaZSM-5 was performed with a maximum exchange level of 90% at 25°C. Subsequent exchange of the sodium for NH+ 4 ions was made with no loss of iron, but the thermal decomposition necessary for conversion of these ammonium ions to protons leads to reduction of Fe3+ to Fe2+. These phenomena were monitored by e.s.c.a., Mössbauer, i.r. of adsorbed pyridine, and temperature-programmed reduction. © 1990 Butterworth-Heinemann.

引用

页码：559 / 564

页数：6

共 16 条

[1] MOSSBAUER-SPECTROSCOPY AND CATALYTIC STUDIES OF IRON-EXCHANGED, SILICON-SUBSTITUTED Y-ZEOLITE [J].