KINETICS OF THE REACTION OF CHLORINE WITH FORMIC-ACID IN AQUEOUS SULFURIC-ACID

被引：16
|
作者：
HOQ, MF
INDU, B
ERNST, WR
NEUMANN, HM
机构：
[1] GEORGIA INST TECHNOL,SCH CHEM ENGN,ATLANTA,GA 30332
[2] GEORGIA INST TECHNOL,SCH CHEM & BIOCHEM,ATLANTA,GA 30332
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 02期
关键词：
D O I：
10.1021/j100155a034
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In sulfuric acid solution, the rate of reaction of chlorine with formic acid is proportional to formic acid and chlorine concentrations and is inversely proportional to the acidity function h}. The kinetic parameters are nearly identical with those for the reduction of bromine to bromide ions by formic acid. The two reactions a appear to follow similar mechanism-equilibrium ionization of formic acid followed by direct reaction of a formate ion with a hologen molecule.
引用
收藏
页码：681 / 683
页数：3
相关论文
共 50 条
  • [31] INVESTIGATION INTO KINETICS OF REACTION BETWEEN FLUORSPAR AND SULFURIC-ACID
    CANDIDO, D
    MATHUR, GP
    INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1974, 13 (01): : 20 - 26
  • [32] KINETICS OF REACTION BETWEEN EUDIALTYE AND DILUTE SULFURIC-ACID
    CHELISHCHEV, NF
    MOTOV, DL
    BUCHKO, ST
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1982, 55 (08): : 1693 - 1695
  • [33] REACTION OF RETINOIC ACID IN SULFURIC-ACID
    TANAKA, H
    KAGECHIKA, H
    SUGITA, K
    HASHIMOTO, Y
    ITAI, A
    SHUDO, K
    TETRAHEDRON LETTERS, 1988, 29 (48) : 6279 - 6282
  • [34] EFFECT OF SALT ON KINETICS OF OXIDATION REACTION OF FORMIC-ACID WITH PERMANGANATE
    RODRIGUEZVELASCO, J
    SANCHEZBURGOS, F
    RUEDARUEDA, M
    GILMARTINEZ, MJ
    ANALES DE QUIMICA, 1978, 74 (06): : 869 - 874
  • [35] THE MECHANISM OF ELECTROCATALYTIC OXIDATION OF FORMIC-ACID ON PT (100) AND PT (111) IN SULFURIC-ACID SOLUTION - AN EMIRS STUDY
    SUN, SG
    CLAVILIER, J
    BEWICK, A
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 240 (1-2): : 147 - 159
  • [36] MECHANISM OF SCHMIDT REACTION .12. REACTION-KINETICS OF BENZALDEHYDE WITH HYDRAZOIC ACID IN AQUEOUS SULFURIC-ACID SOLUTIONS
    KOSHTALEVA, TM
    OSTROVSK.VA
    KOLDOBSK.GI
    GIDASPOV, BV
    ZHURNAL ORGANICHESKOI KHIMII, 1974, 10 (03): : 546 - 550
  • [37] CHLORINE ABSORPTION BY AQUEOUS-SOLUTIONS OF FERROUS SULFATE AND SULFURIC-ACID
    RUBIO, FC
    GONZALEZ, FD
    ANALES DE QUIMICA SERIE A-QUIMICA FISICA Y QUIMICA TECNICA, 1983, 79 (03): : 399 - 404
  • [38] MECHANISMS AND KINETICS OF DECOMPOSITION OF TRIOXALATOCOBALTATE(III) IN AQUEOUS SULFURIC-ACID
    KIMURA, M
    SATO, T
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1973, 46 (02) : 471 - 474
  • [39] KINETICS OF OXIDATION OF FORMIC-ACID BY SILVER(II) IN AQUEOUS PERCHLORIC-ACID SOLUTION
    PELIZZETTI, E
    MENTASTI, E
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (20): : 2086 - 2091
  • [40] FORMIC-ACID REDUCTION .18. FORMIC-ACID REACTION OF PARA (DIALKYLAMINO)AZOBENZENES
    SEKIYA, M
    MATSUDA, O
    SUZUKI, J
    TOMIE, M
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1973, 21 (02) : 372 - 382
12345