KINETICS OF THE REACTION OF CHLORINE WITH FORMIC-ACID IN AQUEOUS SULFURIC-ACID

被引：16

作者：

HOQ, MF

INDU, B

ERNST, WR

NEUMANN, HM

机构：

[1] GEORGIA INST TECHNOL,SCH CHEM ENGN,ATLANTA,GA 30332

[2] GEORGIA INST TECHNOL,SCH CHEM & BIOCHEM,ATLANTA,GA 30332

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 02期

关键词：

D O I：

10.1021/j100155a034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In sulfuric acid solution, the rate of reaction of chlorine with formic acid is proportional to formic acid and chlorine concentrations and is inversely proportional to the acidity function h}. The kinetic parameters are nearly identical with those for the reduction of bromine to bromide ions by formic acid. The two reactions a appear to follow similar mechanism-equilibrium ionization of formic acid followed by direct reaction of a formate ion with a hologen molecule.

引用

页码：681 / 683

页数：3

共 10 条

[1] MICROCALOMETRIC STUDIES OF HEATS OF NEUTRALIZATION AND IONIZATION OF SOME WEAK ACIDS IN HIGHLY DILUTE AQUEOUS SOLUTIONS
CANADY, WJ
PAPEE, HM
LAIDLER, KJ
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1958, 54 (04): : 502 - 506
[2] COTTON FA, 1980, ADV INORGANIC CHEM C, P543
[3] KINETICS OF OXIDATION OF FORMATE IONS WITH BROMINE - H- ACIDITY FUNCTION
COX, BG
MCTIGUE, PT
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (OCT): : 3893 - &
[4] The rate of reaction of bromine with aqueous formic acid.
Hammick, DL
Hutchison, WK
Snell, FR
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1925, 127 : 2715 - 2720
[5] LEBED VI, 1986, ZH FIZ KHIM+, V60, P1299
[6] Masschelein W., 1979, CHLORINE DIOXIDE CHE
[7] NORELL M, 1988, Patent No. 4770868
[8] SWINDELLS R, 1982, Patent No. 4325934
[9] PROTONATION OF WEAK BASES . A STUDY OF PROTONATION OF SOME NITROANILINE INDICATORS AND DETERMINATION OF HO VALUES OF AQUEOUS SULPHURIC ACID
TICKLE, P
BRIGGS, AG
WILSON, JM
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1970, (01): : 65 - &
[10] ZIMMERMAN G, 1957, J AM CHEM SOC, V79, P2063, DOI DOI 10.1021/JA01566A011

← 1 →