THE EFFECT OF LICLO4 CONCENTRATION ON THE ADSORPTION BEHAVIOR OF THIOUREA AT THE MERCURY-ETHANOLIC SOLUTION INTERFACE

被引：9
作者：
SKOMPSKA, M
机构：
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1991年 / 319卷 / 1-2期
关键词：
D O I：
10.1016/0022-0728(91)87088-L
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The capacity-potential behaviour of thiourea at the mercury electrode in ethanolic solutions of LiClO4 is studied. The zero charge potentials, adsorption parameters and DELTA-phi(M-2)-GAMMA-plots are discussed in view of the coadsorption effects of the supporting electrolyte. It is also postulated that thiourea does not desorb from mercury at far negative potentials but only changes the orientation with respect to the surface.
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页码：331 / 339
页数：9
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